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Merck

393541

Sigma-Aldrich

乙酰丙酮镓(III)

99.99% trace metals basis

别名:

2,4-戊二酮酸镓(III), Ga(acac)3

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5 G
$261.00
25 G
$1,200.00

About This Item

线性分子式:
[CH3COCH=C(O-)CH3]3Ga
CAS号:
分子量:
367.05
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

$261.00


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方案

99.99% trace metals basis

表单

solid

反应适用性

core: gallium
reagent type: catalyst

mp

196-198 °C (dec.) (lit.)

SMILES字符串

CC(=O)\C=C(\C)O[Ga](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Ga/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

ZVYYAYJIGYODSD-LNTINUHCSA-K

一般描述

乙酰丙酮镓(III)可作为溶胶-凝胶前驱体合成高纯度GaN纳米线、纳米针和氧化镓薄膜,用于电池、燃料电池和太阳能电池应用。

应用

乙酰丙酮镓(III)可用于
  • 作为前驱体经由溶剂热法合成纳米晶体氧化镓尖晶石,用于光催化、电池正极材料和电催化等多种应用。
  • 原位电还原制造Li金属负极上的LiGa合金层。它抑制锂硫电池负极枝晶形成。
  • 热溶剂合成法(hot-solvent synthesis)制备高效的镓-铂(GaPt3)纳米粒,用作析氢反应的电催化剂。
  • 合成γ-Ga2O3纳米晶体,用于制造钙钛矿太阳能电池的电子传输层。它与钙钛矿顶层形成有效的界面连接,提高电荷传输效率。

象形图

Health hazardExclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Structural Crystallography and Crystal Chemistry
Dymock K and Palenik GJ
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, 30(5), 1364-1366 (1974)
Temperature-controlled catalytic growth of one-dimensional gallium nitride nanostructures using a gallium organometallic precursor
Chang KW,Wu JJ
Applied Physics. A, Materials Science & Processing, 77(6), 769-774 null
Growth of gallium oxide film from gallium acetylacetonate by atomic layer epitaxy.
Nieminen M,et al
Journal of Materials Chemistry, 6, 27-31 null
LowTemperature Catalytic Synthesis of Gallium Nitride Nanowires
The Journal of Physical Chemistry B, 106(32), 7796-7799 (2002)
Matthias Metzger et al.
Analytical and bioanalytical chemistry, 411(19), 4647-4660 (2019-03-09)
The introduction of fluorine into organic molecules leads to new chemical/physical properties. Especially in the field of pharmaceutical as well as technical applications, fluorinated organic substances gain in importance. The OECD identified and categorized 4730 per- and polyfluoroalkyl substances-related CAS

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Nanomaterials are considered a route to the innovations required for large-scale implementation of renewable energy technologies in society to make our life sustainable.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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