369330

N-叔丁基三甲基硅基胺

98%

• 别名: N-(三甲基硅基)-叔丁胺
• 线性分子式: (CH₃)₃SiNHC(CH₃)₃
• CAS号: 5577-67-3
• 分子量: 145.32
• Beilstein: 1734528
• MDL编号: MFCD00054891
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24862959
• NACRES: NA.22

属性

• 质量水平: 100
• 方案: 98%
• 表单: liquid
• 折射率: n20/D 1.406 (lit.)
• 沸点: 118-119 °C (lit.)
• 密度: 0.762 g/mL at 25 °C (lit.)
• 官能团: amine
• SMILES字符串: CC(C)(C)N[Si](C)(C)C
• InChI: 1S/C7H19NSi/c1-7(2,3)8-9(4,5)6/h8H,1-6H3
• InChI key: GVHIREZHTRULPT-UHFFFAOYSA-N

说明

一般描述

N-tert-Butyltrimethylsilylamine (Me₃SiNH-t-Bu) reacts with [Cp*Rh(H₂O)₃](OTf)₂ in acetone to yield a hydroxyl-capped half-cubane [Cp*3Rh₃(μ-OH)3(μ₃-OH)](OTf)₃(t-BuNH₃).[1]

应用

N-tert-Butyltrimethylsilylamine may be used in the preparation of selenium and tellurium chalcogenides[2] and the facile synthesis of N-alkylaminomethylphosphonates.[3]

安全信息

• 象形图: GHS02,GHS05
• 警示用语：: Danger
• 危险声明: H226,H314
• 预防措施声明: P280 - P305 + P351 + P338 - P310
• 危险分类: Flam. Liq. 3 - Skin Corr. 1B
• 储存分类代码: 3 - Flammable liquids
• WGK: WGK 3
• 闪点(°F): 78.8 °F - closed cup
• 闪点(°C): 26 °C - closed cup
• 个人防护装备: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter