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Merck

365696

Sigma-Aldrich

4-甲氧基苯基乙酰氯

98%

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About This Item

线性分子式:
CH3OC6H4CH2COCl
CAS号:
分子量:
184.62
Beilstein:
908061
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

折射率

n20/D 1.54 (lit.)

bp

143 °C/10 mmHg (lit.)

密度

1.208 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(CC(Cl)=O)cc1

InChI

1S/C9H9ClO2/c1-12-8-4-2-7(3-5-8)6-9(10)11/h2-5H,6H2,1H3

InChI 密鑰

CXJOONIFSVSFAD-UHFFFAOYSA-N

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應用

4-Methoxyphenylacetyl chloride may be used in the synthesis of:
  • substituted spiro[4.5]decane
  • 1-(4′-hydroxybenzyl)-6, 7-dihydroxy-1, 2, 3, 4-tetrahydroisoquinoline (higenamine), a cardiotonic principle of aconite root
  • 2,5-naphthyridine
  • (R)-(+)-nor-roefractine

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析证书(COA)

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N Cabedo et al.
Journal of natural products, 61(6), 709-712 (1998-06-27)
(R)-(+)-nor-Roefractine (1) was synthesized by the Bischler-Napieralski route, using asymmetric reduction of the 1, 2-didehydro precursor imine with sodium (S)-N-CBZ-prolinyloxyborohydride. Compound 1 was able to displace [3H]-raclopride (a D2 dopamine receptor-selective ligand) from its specific binding sites in rat striatum
Michael A Letavic et al.
Bioorganic & medicinal chemistry letters, 17(9), 2566-2569 (2007-02-20)
A series of novel tetrahydronaphthyridine-based histamine H(3) ligands that have serotonin reuptake transporter inhibitor activity is described. The 1,2,3,4-tetrahydro-2,6-naphthyridine scaffold is assembled via the addition of a nitrostyrene to a metalated pyridine followed by reduction and cyclization to form the
Synthesis of higenamine, A cardiotonic principle of aconite root.
Chang K-C, et al.
Archives of Pharmacal Research, 7(2), 133-136 (1984)
Synthesis of substituted spiro [4.5] deca-3, 6, 9-triene-2, 8-diones: an expeditious route to the spiro [4.5] decane terpene skeleton.
Haack RA and Beck KR.
Tetrahedron Letters, 30(13), 16505-16508 (1989)

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