360155

二(亚水杨基亚胺酸根-3-丙基)甲基氨基钴(II)

97%

• 别名: [[α,α′-[(Methylimino)bis(trimethylenenitrilo)]di-o-cresolato](2-)]cobalt, [[2,2′-[(Methylimino-κN)bis[3,1-propanediyl(nitrilo-κN)methylidyne]]bis[phenolato-κO]](2-)]cobalt
• 线性分子式: CH₃N[(CH₂)₃N=CHC₆H₄-2-(O)]₂Co
• CAS号: 15391-24-9
• 分子量: 410.38
• MDL號碼: MFCD00134174
• 分類程式碼代碼: 12352300
• PubChem物質ID: 24862151
• NACRES: NA.22

属性

• 化驗: 97%
• 反應適用性: core: cobalt; reagent type: catalyst
• mp: 290-292 °C (lit.)
• SMILES 字串: CN1CCC\N=C\c2ccccc2O[Co]Oc3ccccc3\C=N\CCC1
• InChI: 1S/C21H27N3O2.Co/c1-24(14-6-12-22-16-18-8-2-4-10-20(18)25)15-7-13-23-17-19-9-3-5-11-21(19)26;/h2-5,8-11,16-17,25-26H,6-7,12-15H2,1H3;/q;+2/p-2/b22-16+,23-17+;
• InChI 密鑰: BJSFADUIUGJFKX-VLQAMQNLSA-L

说明

應用

Catalyst for:

• Biomimetic coupled catalytic system
• Cobalt-Schiff base complex catalyzed oxidation of para-substituted phenolics
• Allylation, oxidation, and oxidative cleavages
• Oxidative carbonylation of phenol

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H302 + H312 + H332,H315,H319,H335
• 防範說明: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危險分類: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves