346292

4,4-二甲基-2-苯基-2-噁唑啉

96%

• 经验公式（希尔记法）: C₁₁H₁₃NO
• CAS号: 19312-06-2
• 分子量: 175.23
• MDL编号: MFCD00030446
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24861389
• NACRES: NA.22

属性

• 方案: 96%
• 折射率: n20/D 1.5322 (lit.)
• 沸点: 124 °C/20 mmHg (lit.)
• mp: 20-24 °C (lit.)
• 密度: 1.025 g/mL at 25 °C (lit.)
• SMILES字符串: CC1(C)COC(=N1)c2ccccc2
• InChI: 1S/C11H13NO/c1-11(2)8-13-10(12-11)9-6-4-3-5-7-9/h3-7H,8H2,1-2H3
• InChI key: UGNSMKDDFAUGFT-UHFFFAOYSA-N

说明

一般描述

4,4-Dimethyl-2-phenyl-2-oxazoline is an 2-aryl-2-oxazoline and has been tested as as ligand for the Suzuki coupling reaction of aryl bromides and arylboronic acids.[1] 4,4-Dimethyl-2-phenyl-2-oxazoline forms mildly hygroscopic complexes, of general formulae [ZnX₂(ox)₂] (ox =4,4-Dimethyl-2-phenyl-2-oxazoline), with ether solutions of [ZnX₂] (X = Cl, Br, I).Except ZnI₂, which does not form an isolable complex due to steric reasons.[2]

应用

4,4-Dimethyl-2-phenyl-2-oxazoline may be used in the synthesis of an ester-ammonium salt via rupture of oxazoline ring.[3]

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 10 - Combustible liquids
• WGK: WGK 3
• 闪点(°F): 217.4 °F - closed cup
• 闪点(°C): 103 °C - closed cup
• 个人防护装备: Eyeshields, Gloves, type ABEK (EN14387) respirator filter