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335568

Sigma-Aldrich

2-甲氧基-2-苯乙醇

99%

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About This Item

线性分子式:
C6H5CH(OCH3)CH2OH
CAS号:
2979-22-8
分子量:
152.19
EC 号:
221-030-2
MDL编号:
MFCD00075063
UNSPSC代码:
12352100
PubChem化学物质编号:
24860327
NACRES:
NA.22

方案

99%

表单

liquid

折射率

n20/D 1.519 (lit.)

沸点

237 °C (lit.)

密度

1.061 g/mL at 25 °C (lit.)

官能团

ether
hydroxyl
phenyl

SMILES字符串

COC(CO)c1ccccc1

InChI

1S/C9H12O2/c1-11-9(7-10)8-5-3-2-4-6-8/h2-6,9-10H,7H2,1H3

InChI key

JDTUPLBMGDDPJS-UHFFFAOYSA-N

应用

(S)-2-methoxy-2-phenylethanol was employed as chiral probe for the determination of absolute configuration of active (-) enantiomer of amlodipine.[1] 2-Methoxy-2-phenylethanol was also used in the synthesis of optically active 1,4-dihydropyridines.[2]

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 2

闪点(°F)

208.4 °F - closed cup

闪点(°C)

98 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
00613CJ
04511BV
07514MD
14013JC
11823JU

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Enzymatic resolution of the chiral inductor 2-methoxy-2-phenylethanol.
Monterde MI, et al.
Tetrahedron Asymmetry, 13(10), 1091-1096 (2002)
S Goldmann et al.
Journal of medicinal chemistry, 35(18), 3341-3344 (1992-09-04)
The active (-) enantiomer of amlodipine was originally reported to have R configuration. This does not concur with other 1,4-dihydropyridines with known absolute configuration. This configuration has now been determined by X-ray structural analysis using (1S)-camphanic acid and (S)-2-methoxy-2-phenylethanol as

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