302775

(R)-(-)-2-甲氧基-2-苯乙醇

98%

• 别名: (-)-β-甲氧基苯乙醇
• 线性分子式: C₆H₅CH(OCH₃)CH₂OH
• CAS号: 17628-72-7
• 分子量: 152.19
• MDL编号: MFCD00011550
• UNSPSC代码: 12352112
• PubChem化学物质编号: 24858273
• NACRES: NA.22

属性

• 方案: 98%
• 表单: liquid
• 旋光性: [α]20/D −133°, c = 1 in acetone
• 光学纯度: ee: 99% (GLC)
• 折射率: n20/D 1.52 (lit.)
• 沸点: 65 °C/0.1 mmHg (lit.)
• 密度: 1.05 g/mL at 25 °C (lit.)
• 官能团: ether; hydroxyl; phenyl
• SMILES字符串: CO[C@@H](CO)c1ccccc1
• InChI: 1S/C9H12O2/c1-11-9(7-10)8-5-3-2-4-6-8/h2-6,9-10H,7H2,1H3/t9-/m0/s1
• InChI key: JDTUPLBMGDDPJS-VIFPVBQESA-N

说明

应用

(R)-(-)-2-Methoxy-2-phenylethanol can be employed as a precursor to prepare:

• (−)-3-[(2R)-2-Methoxy-2-phenylethoxy]phenol, a key intermediate for the synthesis of C4-symmetric tetraalkoxy[4]resorcinarenes using boron trifluoride catalyst.[1]
• N-substituent of the 6,7-benzomorphan scaffold that is used as a potent opioid receptor agonist.[2]
• Sodium methoxyphenylethoxide (Na-MPE), which is used as an oxy-initiator in the anionic polymerization of n-hexyl isocyanate.[3]

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H302 + H312 + H332,H315,H319,H335
• 预防措施声明: P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
• 危险分类: Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 10 - Combustible liquids
• WGK: WGK 3
• 闪点(°F): 208.4 °F - closed cup
• 闪点(°C): 98 °C - closed cup
• 个人防护装备: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter