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Merck

296147

Sigma-Aldrich

二甲基亚砜-d 6

99.9 atom % D, contains 0.03 % (v/v) TMS

别名:

DMSO-d6, 二甲基亚砜-d6, 氘代二甲亚砜

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10 X 0.5 ML
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About This Item

线性分子式:
(CD3)2SO
CAS号:
分子量:
84.17
Beilstein:
1237248
EC號碼:
MDL號碼:
分類程式碼代碼:
12191502
PubChem物質ID:
NACRES:
NA.21

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蒸汽壓力

0.42 mmHg ( 20 °C)

品質等級

同位素純度

99.9 atom % D

化驗

99% (CP)

形狀

liquid

自燃溫度

573 °F

包含

0.03 % (v/v) TMS

expl. lim.

42 %

技術

NMR: suitable

雜質

≤0.0250% water
water

折射率

n20/D 1.476 (lit.)

bp

189 °C (lit.)

mp

20.2 °C (lit.)

密度

1.190 g/mL at 25 °C (lit.)

質量偏移

M+6

SMILES 字串

[2H]C([2H])([2H])S(=O)C([2H])([2H])[2H]

InChI

1S/C2H6OS/c1-4(2)3/h1-2H3/i1D3,2D3

InChI 密鑰

IAZDPXIOMUYVGZ-WFGJKAKNSA-N

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一般說明

DMSO-d6是一种氘NMR溶剂,可用于基于NMR的研究和分析。

應用


  • Estimation of dissociation constants (pKa′s) of oximes from proton chemical shifts in dimethyl sulfoxide solution: This research utilizes Dimethyl sulfoxide-d₆ (DMSO-d₆) to determine pKa values of oximes, demonstrating its crucial role in enhancing the accuracy of proton NMR spectroscopy for chemical analysis and research within pharmaceutical contexts (Kurtz AP, D′Silva TD, 1987).

  • Proton nuclear magnetic resonance studies on methylthiohydantoins, thiohydantoins, and hydantoins of amino acids: DMSO-d₆ is extensively employed to investigate the structure and behavior of various hydantoin derivatives in amino acid research, proving essential for understanding protein structures and functions, with implications for both academic and pharmaceutical industries (Suzuki T, Tomioka T, Tuzimura K, 1977).

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儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

190.4 °F

閃點(°C)

88 °C

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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1 of 1

M G Nair et al.
Applied and environmental microbiology, 57(2), 434-439 (1991-02-01)
Two isoflavonoids isolated from clover roots grown under phosphate stress were characterized as formononetin (7-hydroxy,4'-methoxy isoflavone) and biochanin A (5,7-dihydroxy,4'-methoxy isoflavone). At 5 ppm, these compounds stimulated hyphal growth in vitro and root colonization of an undescribed vesicular-arbuscular mycorrhiza, a
Using high-performance quantitative NMR (HP-qNMR?) for certifying traceable and highly accurate purity values of organic reference materials with uncertainties< 0.1%.
Weber M, et al.
Accreditation and Quality Assurance, 18(2), 91-98 (2013)
Diode laser measurements of CD3 quantum yields and internal energy for the dissociation of dimethyl sulfoxide-d6.
Rudolph RN, et al.
J. Chem. Phys. , 106(4), 1346-1352 (1997)
Priya P Netalkar et al.
European journal of medicinal chemistry, 79, 47-56 (2014-04-12)
Air and moisture stable coordination compounds of late first row transition metals, viz. Co(II), Ni(II), Cu(II) and Zn(II), with a newly designed ligand, 2-(2-benzo[d]thiazol-2-yl)hydrazono)propan-1-ol (LH), were prepared and successfully characterized using various spectro-analytical techniques. The molecular structures of the ligand
Barbara Parrino et al.
European journal of medicinal chemistry, 94, 367-377 (2015-03-18)
Three new ring systems, pyrido[2',3':3,4]pyrrolo[1,2-a]quinoxalines, pyrido[3',2':3,4]pyrrolo[1,2-a]quinoxalines and pyrido[2',3':5,6]pyrazino[2,1-a]isoindoles, were synthesized through an aza-substitution on the already active isoindolo-quinoxaline system and in particular in the position 7 or 4 of the isoindole moiety and in position 5 of the quinoxaline portion.

相关内容

NMR spectroscopy elucidates molecular structure and purity via nuclear spin states in a strong magnetic field.

核磁共振光谱通过强磁场中的核自旋状态揭示分子结构和纯度。

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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