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Merck

281409

Sigma-Aldrich

2-碘苯酚

98%

别名:

1-碘-2-羟基苯, 2-羟基碘苯, 间碘苯酚

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$184.00

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5 G
$88.30
25 G
$184.00

About This Item

线性分子式:
IC6H4OH
CAS号:
分子量:
220.01
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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质量水平

方案

98%

表单

solid

沸点

186-187 °C/160 mmHg (lit.)

mp

37-40 °C (lit.)

密度

1.947 g/mL at 25 °C (lit.)

官能团

iodo

SMILES字符串

Oc1ccccc1I

InChI

1S/C6H5IO/c7-5-3-1-2-4-6(5)8/h1-4,8H

InChI key

KQDJTBPASNJQFQ-UHFFFAOYSA-N

一般描述

使用Mo(CO)6作为CO源并在微波辐射下2-碘苯酚与各种炔烃的钯催化羰基化快速环化反应已得到研究[1]

应用

2-碘苯酚可用于合成:
  • 高对映体纯度的芳基2-苯并呋喃基和芳基2-吲哚甲醇[2]
  • 3,3-二取代-2,3-二氢苯并呋喃[3]

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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J Philipp Wagner
Chemistry (Weinheim an der Bergstrasse, Germany), 26(53), 12119-12124 (2020-05-20)
Peroxy radical hydrogen-shifts are pivotal elementary reaction steps in the oxidation of small hydrocarbons in autoignition and the lower atmosphere. Although these reactions are typically associated with a substantial barrier, we demonstrate that the [1,5]H-shift in the peroxy species derived
Chao Fang et al.
Water research, 145, 103-112 (2018-08-20)
Haloacetamides (HAMs), an emerging class of disinfection by-products, have received increasing attention due to their elevated cyto- and genotoxicity. However, only limited information is available regarding the iodinated analogues. This study investigated the formation and speciation of iodinated haloacetamides (I-HAMs)
Microwave-accelerated, palladium-catalyzed carbonylative cyclization reactions of 2-iodophenol with alkynes Rapid and efficient synthesis of chromen-2-one derivatives.
Cao H and Xiao W-J.
Canadian Journal of Chemistry, 83(6-7), 826-831 (2005)
Irene Di Pasquale et al.
Thrombosis research, 173, 42-47 (2018-11-25)
ADAMTS13 deficiency results in unusually large von Willebrand factor (ULVWF) multimers in the circulation and a higher risk of microthrombi due to high shear stress. In patients treated for acquired thrombotic thrombocytopenic purpura (TTP), a persistently severe ADAMTS13 deficiency (<10%)
A K Jain et al.
Environmental technology, 25(1), 15-22 (2004-03-19)
A comparative study of the adsorbents prepared from several industrial wastes for the removal of 2-fluorophenol and 2-iodophenol has been carried out. The results show that maximum adsorption on carbonaceous adsorbent prepared from fertilizer industry waste has been found to

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