255106

二溴硼烷甲硫醚络合物

• 别名: 二溴甲基硫醚化硼络合物
• 线性分子式: (CH₃)₂S · BHBr₂
• CAS号: 55671-55-1
• 分子量: 233.76
• Beilstein: 4449985
• MDL编号: MFCD00011601
• UNSPSC代码: 12352112
• PubChem化学物质编号: 24855287
• NACRES: NA.22

属性

• 表单: solid
• 反应适用性: reagent type: reductant
• mp: 30-35 °C (lit.)
• 官能团: thioether
• SMILES字符串: CSC.BrBBr
• InChI: 1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H
• InChI key: PGSRDLGPKTVELT-UHFFFAOYSA-N

说明

应用

Reactant for:

• Reductive elimination C-C bond forming reactions
• Lithiation-borylation reaction with Hoppe′s lithiated carbamates
• Preparation of boron analogues of uracil
• Boronation reactions for formation of cyclic boronium salts
• Hydroboration reactions
• Ring opening of terminal epoxides

安全信息

• 象形图: GHS02,GHS05
• 警示用语：: Danger
• 危险声明: H228,H261,H314
• 预防措施声明: P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• 危险分类: Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
• 补充剂危害: EUH014
• 储存分类代码: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• 闪点(°F): 78.8 °F - closed cup
• 闪点(°C): 26 °C - closed cup
• 个人防护装备: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges