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Merck

252387

Sigma-Aldrich

五氟丙酸酐

99%

别名:

PFPA, 全氟丙酸酐

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About This Item

线性分子式:
(CF3CF2CO)2O
CAS号:
分子量:
310.05
Beilstein:
1806446
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

liquid

bp

69-70 °C/735 mmHg (lit.)

密度

1.571 g/mL at 25 °C (lit.)

SMILES 字串

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

InChI 密鑰

XETRHNFRKCNWAJ-UHFFFAOYSA-N

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應用

五氟丙酸酐:
  • 用于制备酚酸卤代衍生物,需要测定脑脊液中的一些生物重要酸
  • 用作GC-多离子检测法检测未处理大鼠脑内内源性胺1,2,3,4-四氢异喹啉和1-甲基-1,2,3,4-四氢异喹啉的衍生化试剂
  • 用于通过气液相色谱法同时测定大鼠纹状体多巴胺的主要代谢产物

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
G F Grinstead
Journal of analytical toxicology, 15(6), 293-298 (1991-11-01)
PFPA and acetic anhydride derivatives of morphine and codeine were evaluated with respect to stability, chromatography, potential for analytical interferences by other opiates, and suitability of major fragment ions for analysis by GC/MS with deuterated internal standards and selected ion
J L Villamor et al.
Journal of analytical toxicology, 29(2), 135-139 (2005-05-21)
A new gas chromatography-mass spectrometry method for the simultaneous identification and quantitation of amphetamine (AP), methamphetamine (MA), 3,4-methylenedioxyamphetamine (MDA), 3,4-methylenedioxymethamphetamine (MDMA), and 3,4-methylenedioxyethamphetamine (MDEA) in hair is proposed. Hair was hydrolyzed in 1 M NaOH at 40 degrees C, subjected

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