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方案
97%
折射率
n20/D 1.435 (lit.)
沸点
75-76 °C (lit.)
密度
0.781 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C=C1CCCC1
InChI
1S/C6H10/c1-6-4-2-3-5-6/h1-5H2
InChI key
NFJPEKRRHIYYES-UHFFFAOYSA-N
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一般描述
Hydration rate of methylenecyclopentane has been measured spectrophotometrically in aqueous perchloric acid. Trost′s palladium-mediated methylenecyclopentane annelation to the nitroalkene yields methylenecyclopentane derivative.
应用
Methylenecyclopentane has been used in total synthesis of (±)-cephalotaxin.
警示用语:
Danger
危险声明
危险分类
Asp. Tox. 1 - Flam. Liq. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-0.4 °F - closed cup
闪点(°C)
-18 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
COMPARISON OF THE TRANSITION-STATE ENERGIES OF ACID-CATALYZED HYDRATIONS OF SOME 1-METHYLCYCLOALKENES AND METHYLENECYCLOALKANES.
Lajunen M and Himottu M.
Acta Chemica Scandinavica, 41(5), 252-258 (1987)
The total synthesis of cephalotaxine.
J Auerbach et al.
Journal of the American Chemical Society, 94(20), 7172-7173 (1972-10-04)
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