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Merck

238600

Sigma-Aldrich

4-甲氧基苯异氰酸酯

99%

别名:

1-异氰酸基-4-甲氧基苯, 4-异氰酸苯甲醚, 4-甲氧基异氰酸酯, 对异氰酸苯甲酯, 对甲氧基苯基异氰酸酯

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About This Item

线性分子式:
CH3OC6H4NCO
CAS号:
分子量:
149.15
Beilstein:
471920
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.548 (lit.)

bp

106-110 °C/16 mmHg (lit.)

密度

1.151 g/mL at 25 °C (lit.)

SMILES 字串

COc1ccc(cc1)N=C=O

InChI

1S/C8H7NO2/c1-11-8-4-2-7(3-5-8)9-6-10/h2-5H,1H3

InChI 密鑰

FMDGXCSMDZMDHZ-UHFFFAOYSA-N

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一般說明

基于四氢嘧啶-2-亚基通过CO2保护的N-杂环卡宾的4-异甲氧基苯基异氰酸酯的环三聚已被报道

應用

4-甲氧基苯基异氰酸酯可用于制备:
  • 6H-吲哚并[2,3-b]喹啉
  • 1-[2-(2-呋喃基)-8-甲基-9-取代的-8H-吡唑并[4,3-e]-1,2,4-三唑并[1,5-c] 嘧啶-5-基]-3-(4-甲氧基苯基)脲

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Chongsheng Shi et al.
The Journal of organic chemistry, 64(3), 925-932 (2001-10-25)
Thermolysis of the carbodiimide 9a in gamma-terpinene at 138 degrees C produced 2-(phenylamino)quinoline (11a, 49%) and the parent 6H-indolo[2,3-b]quinoline (14a, 16%). Apparently, 11a was produced via the biradical 10a followed by hydrogen-atom abstraction from gamma-terpinene. A two-step biradical pathway through
Geng Li et al.
Chirality, 27(8), 518-522 (2015-06-04)
Ten novel xylan bisphenylcarbamate derivatives bearing meta- and para-substituents on their phenyl groups were synthesized and their chiral recognition abilities were evaluated as the chiral stationary phases (CSPs) for high-performance liquid chromatography (HPLC) after coating them on macroporous silica. The
Pier Giovanni Baraldi et al.
Journal of medicinal chemistry, 46(7), 1229-1241 (2003-03-21)
In the past few years, our group has been involved in the development of A(2A) and A(3) adenosine receptor antagonists which led to the synthesis of SCH58261 (5-amino-7-(2-phenylethyl)-2-(2-furyl)pyrazolo[4,3-e]-1,2,4-triazolo[1,5-c]pyrimidine, 61), potent and very selective at the A(2A) receptor subtype, and N(8)-substituted-pyrazolo[4,3-e]-1,2,4-triazolo[1,5-c]pyrimidines-N(5)-urea
Bhasker Bantu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 15(13), 3103-3109 (2009-02-13)
Catalytic rivals: Both CO(2)-protected tetrahydropyrimidin-2-ylidene-based N-heterocyclic carbenes (NHCs) and Sn(II)-1,3-dimesitylimidazol-2-ylidene, as well as Sn(II)-1,3-dimesitylimidazolin-2-ylidene complexes (example displayed), have been identified as truly latent catalysts for polyurethane (PUR) synthesis rivaling all existing systems both in activity and latency.A series of CO(2)-protected

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