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Merck

237906

Sigma-Aldrich

氯甲酸苯酯

97%

别名:

苯基氯甲酸酯

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5 G
$68.70
100 G
$99.20

About This Item

线性分子式:
ClCOOC6H5
CAS号:
分子量:
156.57
Beilstein:
606778
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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蒸汽密度

1 (vs air)

质量水平

蒸汽压

1.22 psi ( 20 °C)
1.67 psi ( 55 °C)

方案

97%

表单

liquid

折射率

n20/D 1.511 (lit.)

沸点

74-75 °C/13 mmHg (lit.)

密度

1.248 g/mL at 25 °C (lit.)

官能团

chloro
phenoxy

储存温度

2-8°C

SMILES字符串

ClC(=O)Oc1ccccc1

InChI

1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H

InChI key

AHWALFGBDFAJAI-UHFFFAOYSA-N

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一般描述

研究了氯甲酸苯酯在水-乙二醇、阳离子、两性离子、非离子和阴离子胶束溶液中的自发水解动力学,[1]

应用

氯甲酸苯酯已经用于聚(2-(苯氧羰基氧基)甲基丙烯酸乙酯)[2]和苯基-(4-乙烯基苯基)碳酸[3]的合成。

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险分类

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

156.2 °F - closed cup

闪点(°C)

69 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Amalia Rodríguez et al.
Langmuir : the ACS journal of surfaces and colloids, 20(23), 9945-9952 (2004-11-03)
The spontaneous hydrolysis of phenyl chloroformate was studied in water-ethylene glycol, EG, cationic, zwitterionic, nonionic, and anionic micellar solutions, the surfactants being tetradecyltrimethylammonium bromide, tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate, tricosaoxyethylene glycol ether, and sodium dodecyl sulfate. The dependence of the observed rate constant on
Functional polymethacrylates as bacteriostatic polymers.
Adelmann R, et al.
Eur. Polymer J., 45(11), 3093-3107 (2009)
Synthesis and ligand recognition of paracetamol selective polymers: semi-covalent versus non-covalent molecular imprinting.
Rosengren-Holmberg JP, et al.
Organic & Biomolecular Chemistry, 7(15), 3148-3155 (2009)
B Boettcher et al.
Analytical biochemistry, 138(2), 449-450 (1984-05-01)
An improved synthesis of L-2- oxothiazolidine -4-carboxylic acid is described. The new procedure, which leads to excellent yields of product, does not require the use of phosgene. The new method is thus less hazardous than the original one, and is
Luis García-Río et al.
Langmuir : the ACS journal of surfaces and colloids, 21(17), 7672-7679 (2005-08-11)
A study was carried out on the solvolysis of substituted phenyl chloroformates in AOT/isooctane/water microemulsions. (AOT is the sodium salt of bis(2-ethyhexyl)sulfosuccinate.) The results obtained have been interpreted by taking into account the distribution of the chloroformates between the continuous

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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