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Merck

232599

Sigma-Aldrich

甲氧基乙酸乙酯

97%

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10 G
$98.00

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10 G
$98.00

About This Item

线性分子式:
CH3OCH2COOC2H5
CAS号:
分子量:
118.13
Beilstein:
1744761
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

$98.00


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品質等級

化驗

97%

形狀

liquid

折射率

n20/D 1.401 (lit.)

bp

44-45.5 °C/9 mmHg (lit.)

密度

1.007 g/mL at 25 °C (lit.)

官能基

ester
ether

SMILES 字串

CCOC(=O)COC

InChI

1S/C5H10O3/c1-3-8-5(6)4-7-2/h3-4H2,1-2H3

InChI 密鑰

JLEKJZUYWFJPMB-UHFFFAOYSA-N

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應用

Ethyl methoxyacetate was used:
  • as acyl donor during the preparation of enantiomers of several phenylethylamines[1]
  • as acylation reagent for the aminolysis of 1-phenylethanamine[2]
  • in an industrial, lipase-catalysed kinetic resolution of primary amine[3]

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

114.8 °F - closed cup

閃點(°C)

46 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ulf Hanefeld
Organic & biomolecular chemistry, 1(14), 2405-2415 (2003-09-06)
Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of all
Lourdes Muñoz et al.
Organic & biomolecular chemistry, 9(23), 8171-8177 (2011-10-06)
Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the 4-hydroxyderivative of amphetamine
A Basler
Mutation research, 174(1), 11-13 (1986-05-01)
Chinese hamsters were exposed to acetone, methyl ethyl ketone, ethyl acetate and 2-methoxy ethyl acetate, known to be strong inducers of aneuploidy in the yeast Saccharomyces cerevisiae. All solvents yielded negative results in the micronucleus test, whereas the vinca alkaloid
M J Kang et al.
Rapid communications in mass spectrometry : RCM, 15(15), 1327-1333 (2001-07-24)
Sample preparation methods and data acquisition protocols were optimized for the application of matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOFMS) to high-throughput quantitative analysis of low molecular mass substrates and products of an enzyme-catalyzed reaction. Using a deuterlum-labeled internal standard
Saija Sirén et al.
Molecules (Basel, Switzerland), 25(4) (2020-02-23)
The enantiomers of aromatic 4-dibenzocyclooctynol (DIBO), used for radiolabeling and subsequent conjugation of biomolecules to form radioligands for positron emission tomography (PET), were separated by kinetic resolution using lipase A from Candida antarctica (CAL-A). In optimized conditions, (R)-DIBO [(R)-1, ee

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