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Merck

226637

Sigma-Aldrich

亚硝酸丁酯

95%

别名:

亚硝酸正丁酯

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25 G
$80.90
100 G
$269.00

About This Item

线性分子式:
CH3(CH2)3ONO
CAS号:
分子量:
103.12
Beilstein:
1701036
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$80.90


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蒸汽压

760 mmHg ( 78 °C)

质量水平

方案

95%

表单

liquid

折射率

n20/D 1.376 (lit.)

沸点

78 °C (lit.)

溶解性

alcohol: miscible(lit.)
diethyl ether: miscible(lit.)

密度

0.882 g/mL at 25 °C (lit.)

官能团

O-nitroso
nitroso

储存温度

2-8°C

SMILES字符串

CCCCON=O

InChI

1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3

InChI key

JQJPBYFTQAANLE-UHFFFAOYSA-N

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一般描述

亚硝酸丁酯的光解离动力学的通过时间分辨傅立叶变换红外(TR-FTIR)发射光谱进行了研究[1]。亚硝酸丁酯对甲基维生素B12和5-甲基四氢叶酸的影响已有研究[2]

象形图

FlameSkull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

8.6 °F - closed cup

闪点(°C)

-13 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

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Tsuyoshi Taniguchi et al.
Chemical communications (Cambridge, England), 49(22), 2198-2200 (2013-02-12)
A method for direct functionalization of three positions including an unactivated C-H bond of aliphatic alkenes using tert-butyl nitrite and molecular oxygen to give γ-lactols has been developed. The present reaction proceeds through a sequence of radical processes involving oxynitration
J D Osterloh et al.
Journal of pharmaceutical sciences, 74(7), 780-782 (1985-07-01)
The uptake of butyl nitrite by rats (500 g, one rat/chamber) was determined over a 5-min exposure period. About 44% of the starting amount (771-3855 ppm) of n-butyl nitrite was consumed in 5 min. Three rats per exposure concentration were
Min Ji et al.
The Journal of chemical physics, 130(17), 174314-174314 (2009-05-12)
We report on the photodissociation dynamics study of n-butyl nitrite and isoamyl nitrite by means of time-resolved Fourier transform infrared (TR-FTIR) emission spectroscopy. The obtained TR-FTIR emission spectra of the nascent NO fragments produced in the 355 nm laser photolysis
B A Meloche et al.
Xenobiotica; the fate of foreign compounds in biological systems, 23(8), 863-871 (1993-08-01)
1. The addition of n-butyl nitrite (BN) to isolated rat hepatocytes caused rapid S-nitrosyl glutathione (GSNO) formation, then a concomitant decrease in protein thiols, followed by a marked ATP depletion. Cytotoxic concentrations of BN also caused lipid peroxidation after a
G R Newell et al.
The American journal of medicine, 78(5), 811-816 (1985-05-01)
Early reports of the acquired immune deficiency syndrome (AIDS) in homosexual men suggested that the cause might be related to homosexual life-style practices, including use of recreational drugs. Inhalation of volatile nitrites is a possible contributing factor in AIDS because

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