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Merck

224758

Sigma-Aldrich

三(2,2′——联吡啶二氯钌 (II) 六水合物

powder

别名:

Ru(BPY)3, 三(2,2′-联吡啶)氯化钌(II) 六水合物, 三联吡啶氯化钌

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250 MG
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250 MG
$75.20
1 G
$210.00
5 G
$655.00

About This Item

经验公式(希尔记法):
C30H24Cl2N6Ru · 6H2O
CAS号:
分子量:
748.62
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

$75.20


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表单

powder

反应适用性

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C (lit.)

光触媒活化

450 nm

SMILES字符串

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2

InChI key

WHELTKFSBJNBMQ-UHFFFAOYSA-L

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一般描述

三(2,2′-联吡啶)二氯化钌(II) 六水合物是一种金属络合物,被用作发光染料。处于基态的金属络合物能够被可见光激发,形成自旋允许激发态。该激发态经过无辐射去活化,非常快速地形成自旋禁阻长期发光激发态。它被广泛用于电发光设备中。[1]

应用

  • 合成用于氧化酶生物传感器的复合催化剂。[2]
  • 用作生物分析中多重信号传导的发光体。[3]
  • 用于活细胞中的氧气评估。[4][5][6]
有关更多信息,请访问Teshik Yoon教授Corey Stephenson教授的个人产品网站。

产品适配我们的光反应器系列:包括Penn PhD (Z744035) & SynLED 2.0 (Z744080)

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产品编号
说明
价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Stéphanie Heux et al.
Applied and environmental microbiology, 77(19), 7040-7049 (2011-08-16)
Miniaturization and high-throughput screening are currently the focus of emerging research areas such as systems biology and systems biotechnology. A fluorescence-based screening assay for the online monitoring of oxygen and pH and a numerical method to mine the resulting online
A Theoretical and Experimental Framework for Understanding Electrogenerated Chemiluminescence (ECL) Emission at Bipolar Electrodes
Mavre F, et al
Analytical Chemistry, 81, 6218-6225 (2009)
Attapulgite Clay Combined with Tris(2,2'bipyridyl)ruthenium(II) for the Enhancement of the
Electrogenerated Chemiluminescence Sensing
Gu B. et al
International Journal of Electrochemical Science, 7, 6202-6213 (2012)
Old Molecules, New Concepts:[Ru (bpy) 3] 2+ as a Molecular Encoder-Decoder
Ceroni, P., Bergamini, G., & Balzani, V.
Angewandte Chemie (International Edition in English), 121(45), 8668-8670 (2009)
Novel organic-inorganic hybrid material based on tris (2, 2'-bipyridyl) dichlororuthenium (II) hexahydrate and Dawson-type tungstophosphate K 7[H4PW18O62]? 18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam, M., & Easton, E. B.
Sensors and Actuators B, Chemical, 161(1), 520-527 (2012)

相关内容

Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

Yoon lab exploits visible light photochemistry for unique chemical transformations.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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