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Merck
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209929

Sigma-Aldrich

2-乙氧基四氢呋喃

99%

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About This Item

经验公式（希尔记法）:
C6H12O2
CAS号:
13436-46-9
分子量:
116.16
EC 号:
236-569-9
MDL编号:
MFCD00005360
UNSPSC代码:
12352100
PubChem化学物质编号:
24852603

方案

99%

表单

liquid

折射率

n20/D 1.414 (lit.)

沸点

170-172 °C (lit.)

密度

0.908 g/mL at 25 °C (lit.)

SMILES字符串

CCOC1CCCO1

InChI

1S/C6H12O2/c1-2-7-6-4-3-5-8-6/h6H,2-5H2,1H3

InChI key

JQYYUWHWGCJWTN-UHFFFAOYSA-N

一般描述

2-Ethoxytetrahydrofuran undergoes Ln(OTf)3-catalyzed-Povarov coupling reaction with anilines and cyclopentadiene to yield tetrahydroquinolines[1]. Transacetalization of 2-ethoxytetrahydrofuran with various alcohols catalyzed by Fe(ClO4)3 has been reported[2].

应用

2-Ethoxytetrahydrofuran was used to investigate quantitative, regioselective, O-acylative cleavage of tetrahydrofurans using organic acid halides in the presence of Bi(III) halides[3].

象形图

Flame
GHS02

警示用语：

Danger

危险声明

H225

危险分类

Flam. Liq. 2

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

60.8 °F - closed cup

闪点(°C)

16 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
48196MM
00226CH
00212JG
00113JS
13919HQ

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Bi (III) halides as efficient catalysts for the O-acylative cleavage of tetrahydrofurans: an expeditious entry to tetralins.
Coles SJ, et al.
Tetrahedron, 61(18), 4447-4452 (2005)
Fe3+-Catalyzed transacetalization of 2-alkoxytetrahydrofurans with alcohols.
Yamanaka D, et al.
Tetrahedron Letters, 49(1), 53-56 (2008)
Lanthanide (III)-catalyzed multi-component aza-Diels-Alder reaction of aliphatic N-arylaldimines with cyclopentadiene.
Powell DA and Batey RA.
Tetrahedron Letters, 44(41), 7569-7573 (2003)

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