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Merck

201138

Sigma-Aldrich

六氟磷酸铵

≥95%

别名:

Ammonium hexafluophosphate, Ammonium hexafluorophosphate V, Ammonium phosphorus hexafluoride, Ammoniumhexafluorophosphate

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25 G
$139.00
100 G
$417.00
500 G
$1,640.00

About This Item

线性分子式:
NH4PF6
CAS号:
分子量:
163.00
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38070413
PubChem化学物质编号:
NACRES:
NA.22

$139.00


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方案

≥95%

表单

solid

浓度

≤100%

溶解性

water: soluble ca.50 g/L

密度

2.18 g/mL at 25 °C (lit.)

SMILES字符串

[H][N+]([H])([H])[H].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.H3N/c1-7(2,3,4,5)6;/h;1H3/q-1;/p+1

InChI key

NIZXKAYXSNUDOU-UHFFFAOYSA-O

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应用

六氟磷酸铵(NH4PF6)可以用作制备以下物质的前体:
  • 金属络合物,特别是铱和铑络合物。[1][2][3]       
  • 阻燃纤维素基材料。[4]       
  • 环氨基和亚氨基六氟磷酸铵盐。[5]        
  • 聚合物负载的铱异构化催化剂,可用于选择性 反式 芳基烯丙基衍生物的异构化。[6]

象形图

Corrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A polymer-supported iridium catalyst for the stereoselective isomerisation of double bonds
Baxendale IR, et al.
Synlett, 2002(03), 0516-0518 (2002)
Preparations of iridium complexes containing phenanthroline ancillary ligands and electrical properties of cationic iridium-based light-emitting electrochemical cells
Park S, et al.
Surface and Interface Analysis : SIA, 44(11-12), 1479-1482 (2012)
Electronic absorption and emission spectral studies of square-planar Rhodium (I) and Iridium (I) complexes. Evidence for a charge-transfer emitting state
Geoffroy GL, et al.
Journal of the American Chemical Society, 96(10), 3105-3108 (1974)
A simple and efficient one-step protocol for the preparation of alkyl-substituted ammonium tetrafluoroborate and hexafluorophosphate salts
Saba Shahrokh, et al.
Journal of Fluorine Chemistry, 153, 168-171 (2013)
Accelerated luminophore discovery through combinatorial synthesis.
Lowry, Michael S et al.
Journal of the American Chemical Society, 126(43), 14129-14135 (2004)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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