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Merck
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文件

199958

Sigma-Aldrich

六羰基钼

98%

别名:

羰化钼

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About This Item

线性分子式:
Mo(CO)6
CAS号:
13939-06-5
分子量:
264.00
EC號碼:
237-713-3
MDL號碼:
MFCD00003466
分類程式碼代碼:
12352103
PubChem物質ID:
24851946

蒸汽密度

9.1 (vs air)

化驗

98%

形狀

solid

反應適用性

core: molybdenum
reagent type: catalyst

bp

156 °C (lit.)

mp

150 °C (dec.) (lit.)

密度

1.96 g/mL at 25 °C (lit.)

SMILES 字串

[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/6CO.Mo/c6*1-2;

InChI 密鑰

KMKBZNSIJQWHJA-UHFFFAOYSA-N

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一般說明

六羰基钼是一种白色结晶固体，在 150 ° C 下熔融，密度为 1.96 gm/cc，不溶于水和可溶在大多数有机溶剂中。

應用

用于二氧化硅的接枝，作为烯烃环氧化的催化剂， 从液体燃料中吸附有机硫化合物，作为生产有机钼染料和热分解镀钼的前体。

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險聲明

H331

危險分類

Acute Tox. 3 Inhalation

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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Selective adsorption of dibenzothiophene by functionalized metal organic frameworks sorbents
Shi F, et al
Applied Catalysis. B, Environmental, 103(3-4), 261-265 (2011)
Epoxidation of DL-limonene using an indenyl molybdenum(II) tricarbonyl complex as catalyst precursor
Abrantes M, et al
Catalysis Communications, 15(1), 64-67 (2011)
Advanced Synthesis & Catalysis, 352(10), 1759-1769 (2010)
Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
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