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Merck

197378

Sigma-Aldrich

苦味酸

moistened with water, ≥98%

别名:

2,4,6-三硝基苯酚, PA

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$386.00

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国内现货,预计发货时间2025年4月22日详情


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100 G
$129.00
500 G
$386.00

About This Item

线性分子式:
(O2N)3C6H2OH
CAS号:
分子量:
229.10
颜色索引号:
10305
Beilstein:
423400
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

$129.00


国内现货,预计发货时间2025年4月22日详情


获取大包装报价

蒸汽密度

7.9 (vs air)

质量水平

蒸汽压

1 mmHg ( 195 °C)

方案

≥98%

表单

powder or crystals (with a top layer of Liquid)

包含

≥35% water

expl. lim.

0.01 %

浓度

≥50-<70%

mp

122-123 °C (dried material) (lit.)

溶解性

alcohol: 1 (g/12 mL)(lit.)
benzene: 1 g/10 mL
chloroform: 1 (g/35 mL)
diethyl ether: 1 (g/65 mL)

密度

1.763 g/cm3

官能团

nitro

SMILES字符串

Oc1c(cc(cc1[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H

InChI key

OXNIZHLAWKMVMX-UHFFFAOYSA-N

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一般描述

苦味酸(PA,2,4,6-三硝基苯酚)[1]是一种多硝基芳香酸它本质上具有强酸性。由于它易溶于水,因此很容易污染环境。[2]研究人员已经报道过通过三咪唑盐[2]、荧光 [3+2] 自组装纳米级有机笼[3]和罗丹明传感器[4]对 PA 进行灵敏检测。它广泛用于分光光度法和萃取分光光度法测定各种有机化合物。[1]

应用

苦味酸可用于比索洛尔的定量测定[5]
苦味酸已用于制备 Bouin′ 固定液[6]和苦味酸/叠氮化钠/多壁碳纳米管。[7]

象形图

FlameSkull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Desen. Expl. 1

储存分类代码

4.1A - Other explosive hazardous materials

WGK

WGK 2

闪点(°F)

302.0 °F - closed cup

闪点(°C)

150 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Preparation and evaluation of hybrid composites of chemical fuel and multi-walled carbon nanotubes in the study of thermopower waves.
Hwang H, et al.
Journal of Visualized Experiments, 98, e52818- e52818 (2015)
Mario Sanhueza et al.
Journal of visualized experiments : JoVE, (111)(111), doi:10-doi:10 (2016-05-24)
Most studies on morphogenesis rely on qualitative descriptions of how anatomical traits are affected by the disruption of specific genes and genetic pathways. Quantitative descriptions are rarely performed, although genetic manipulations produce a range of phenotypic effects and variations are
Bijan Roy et al.
The Journal of organic chemistry, 78(3), 1306-1310 (2013-01-12)
Two new anthracene-functionalized fluorescent tris-imidazolium salts have been synthesized, characterized, and proven to be selective sensors for picric acid, which is a common constituent of many powerful explosives. Theoretical studies revealed an unusual ground-state electron transfer from picrate anion to
Koushik Acharyya et al.
Chemical communications (Cambridge, England), 50(99), 15788-15791 (2014-11-06)
Dynamic covalent imine chemistry has been utilized to synthesize a fluorescent [3+2] self-assembled nanoscopic organic cage. The fluorescent nature of the reduced analogue of the cage was further exploited for the highly selective detection of the explosive picric acid (PA).
Alina-Diana Panainte et al.
Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi, 117(2), 520-524 (2013-12-18)
Bisoprolol is a drug belonging to beta blockers drugs used primarily for the treatment of cardiovascular diseases. A spectrophotometric method for quantitative determination of bisoprolol was developed based on the formation of a complex combination between bisoprolol and picric acid.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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