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Merck

189138

Sigma-Aldrich

四丁基溴化膦

greener alternative

98%

别名:

Tetra-n-butylphosphonium bromide

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About This Item

线性分子式:
(CH3CH2CH2CH2)4P(Br)
CAS号:
分子量:
339.33
Beilstein:
4160474
EC號碼:
MDL號碼:
分類程式碼代碼:
12352001
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

solid

環保替代產品特色

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

100-103 °C (lit.)

環保替代類別

SMILES 字串

[Br-].CCCC[P+](CCCC)(CCCC)CCCC

InChI

1S/C16H36P.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1

InChI 密鑰

RKHXQBLJXBGEKF-UHFFFAOYSA-M

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我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处以获取更多信息。

應用

四丁基溴化膦是一种季盐,可用作:
  • 作为分散钌催化剂的介质,用于通过钌熔融催化( ruthenium melt catalysis)由合成气合成乙二醇。
  • 作为二氧化硅或氧化铝上负载的催化剂,用于烷基氯的卤素交换反应合成烷基溴。
  • 与不同比例的1,3-二甲基脲混合以合成用于捕获NO气体各种离子液体。
  • 作为氢键受体与氢键供体乙酰丙酸一起用于制备深共晶溶剂,从而分离出甲苯/己烷混合物中的甲苯。
  • 制备离子型半笼型水合物,

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Repr. 2 - Skin Sens. 1B

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

554.0 °F - closed cup

閃點(°C)

290 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


分析证书(COA)

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Facile continuous process for gas phase halogen exchange over supported alkyl phosphonium salts
Sharma P and Sasson Y
Royal Society of Chemistry Advances, 8(5), 2824-2828 (2018)
Yunqing Kang et al.
ACS nano (2020-12-15)
Amorphous bimetallic borides are an emerging class of catalytic nanomaterial that has demonstrated excellent catalytic performance due to its glass-like structure, abundant unsaturated active sites, and synergistic electronic effects. However, the creation of mesoporous Earth-abundant bimetallic metal borides with tunable
Robert Biczak et al.
Environmental science and pollution research international, 27(27), 34182-34198 (2020-06-20)
This paper presents the influence of two bromides, tetrabutylammonium and tetrabutylphosphonium, on the growth and development of cucumber seedlings. The tests were performed at two dates, i.e. 10 and 20 days, after the introduction of increasing amounts of ionic liquids (ILs)
1, 3-Dimethylurea tetrabutylphosphonium bromide ionic liquids for NO efficient and reversible capture
Jiang B, et al.
Energy and Fuels, 30(1), 735-739 (2016)
Yoshiro Yasaka et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 19(13), 1674-1682 (2018-04-25)
The mechanism of CO2 absorption by a formate ionic liquid, [P4444 ]HCOO, was studied by Raman spectroscopy. The band area for the symmetric CO2 stretching of the formate anion linearly decreases with the CO2 loading. From the slope of the

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