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Merck

169897

Sigma-Aldrich

1-苯基-1H-四唑-5-硫醇

98%

别名:

1-苯基-5-巯基四氮唑, 1-苯基四氮唑-5-硫醇, 5-巯基-1-苯基四氮唑

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About This Item

经验公式(希尔记法):
C7H6N4S
CAS号:
分子量:
178.21
Beilstein:
139068
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

方案

98%

表单

powder

mp

145 °C (dec.) (lit.)

溶解性

ethanol: soluble 5%, clear, colorless to faintly yellow

SMILES字符串

Sc1nnnn1-c2ccccc2

InChI

1S/C7H6N4S/c12-7-8-9-10-11(7)6-4-2-1-3-5-6/h1-5H,(H,8,10,12)

InChI key

GGZHVNZHFYCSEV-UHFFFAOYSA-N

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一般描述

1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution[1].

应用

1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions[2]. It was also used in the synthesis of metalated tetradecyl sulfone[3].

象形图

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警示用语:

Danger

危险分类

Aquatic Chronic 4 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Sens. 1

储存分类代码

4.1A - Other explosive hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A formal synthesis of 3-O-(4-methoxybenzyl)-azidosphingosine by a modified Julia olefination.
Compostella F, et al.
Tetrahedron, 58(22), 4425-4428 (2002)
The inhibitive effect of some tetrazole derivatives towards Al corrosion in acid solution: Chemical, electrochemical and theoretical studies.
Khaled KF and Al-Qahtani MM.
Materials Chemistry and Physics, 113(1), 150-158 (2009)
Mohammad M Khodaei et al.
The Journal of organic chemistry, 73(7), 2527-2532 (2008-03-05)
In the presence of 1-phenyl-5-mercaptotetrazole as a nucleophile, electrochemical oxidations of 1,2- and 1,4-dihydroxybenzenes have been investigated in aqueous solution using cyclic voltammetry and controlled-potential coulometry. The voltammetric results indicate that an electrooxidative/Michael-type sequential reaction occurs between the mercaptide anion
Total synthesis of ambruticin.
Eun Lee et al.
Angewandte Chemie (International ed. in English), 41(1), 176-178 (2002-12-20)
K Nesmĕrák et al.
Folia microbiologica, 45(2), 138-142 (2001-03-29)
The antifungal effect of substituted 1-phenyl-5-mercaptotetrazoles was tested with Candida tropicalis, C. pseudotropicalis, C. mogii, Trichosporon cutaneum, Cryptococcus albidus and S. cerevisiae. Candida strains exhibited the lowest sensitivity to the compounds; the most sensitive was S. cerevisiae. The MIC values

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