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167150

Sigma-Aldrich

1-溴-4-硝基苯

99%

别名:

1-溴-4-硝基苯, 1-硝基-4-溴苯, 4-溴-1-硝基苯, 4-硝基-1-溴苯, 4-硝基溴苯, 4-硝苯基溴, 对溴硝基苯, 对硝苯基溴

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5 G
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About This Item

线性分子式:
BrC6H4NO2
CAS号:
586-78-7
分子量:
202.01
Beilstein:
636964
EC 号:
209-583-8
MDL编号:
MFCD00007280
UNSPSC代码:
12352100
PubChem化学物质编号:
24850195
NACRES:
NA.22

$70.90

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质量水平

200

方案

99%

表单

solid

沸点

255-256 °C (lit.)

mp

124-126 °C (lit.)

官能团

bromo
nitro

SMILES字符串

[O-][N+](=O)c1ccc(Br)cc1

InChI

1S/C6H4BrNO2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H

InChI key

ZDFBKZUDCQQKAC-UHFFFAOYSA-N

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相关类别

一般描述

用循环伏安法研究了 1-溴-4-硝基苯在离子液体中锌微电极上的电化学还原 [1]。1-溴-4-硝基苯与呋喃-2-基三丁基锡（以 Dabco（三乙二胺）为配体）发生钯催化的斯蒂尔交叉偶联反应 [2]。它与 p -甲酚反应生成 1-甲基-4-（4-硝基苯氧基）苯 [3]。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H302

危险分类

Acute Tox. 4 Oral

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCJ4188
BCBP3770V
1451718V
1451719V
1451719

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Jin-Heng Li et al.
The Journal of organic chemistry, 70(7), 2832-2834 (2005-03-25)
[reaction: see text] An efficient Pd(OAc)2/Dabco-catalyzed Stille cross-coupling reaction procedure has been developed. In the presence of Pd(OAc)2 and Dabco (triethylenediamine), various aryl halides including aryl iodides, aryl bromides, and activated aryl chlorides were coupled efficiently with organotin compounds to
Evgeniy G Gordeev et al.
PloS one, 13(6), e0198370-e0198370 (2018-06-08)
Additive manufacturing with fused deposition modeling (FDM) is currently optimized for a wide range of research and commercial applications. The major disadvantage of FDM-created products is their low quality and structural defects (porosity), which impose an obstacle to utilizing them
Sven Ernst et al.
Physical chemistry chemical physics : PCCP, 16(10), 4478-4482 (2014-01-30)
The electrochemical reduction of 1-bromo-4-nitrobenzene (p-BrC6H4NO2) at zinc microelectrodes in the [C4mPyrr][NTf2] ionic liquid was investigated via cyclic voltammetry. The reduction was found to occur via an EC type mechanism, where p-BrC6H4NO2 is first reduced by one electron, quasi-reversibly, to
Synthesis of diaryl ethers using an easy-to-prepare, air-stable, soluble copper (I) catalyst.
Gujadhur R and Venkataraman D.
Synthetic Communications, 31(18), 2865-2879 (2001)
Xiao Yan et al.
Physical chemistry chemical physics : PCCP, 22(11), 6222-6230 (2020-03-05)
Unveiling the reaction mechanism is significant for developing high-performance catalysts. In this paper, a series of precisely controlled PdxM147-x (M = Cu, Pt, Au, Rh, Ru) dendrimer encapsulated nanoparticles (DENs) has been successfully synthesized. The mechanisms of PdxM147-x as catalysts
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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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