推荐产品
等級
technical grade
化驗
90%
形狀
solid
mp
43-47 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
O=C(OCc1ccccc1)\N=N\C(=O)OCc2ccccc2
InChI
1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2/b18-17+
InChI 密鑰
IRJKSAIGIYODAN-ISLYRVAYSA-N
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一般說明
偶氮二甲酸二苄酯可以与糖发生[4+2]环加成反应，生成2-氨基糖苷。
應用
偶氮二甲酸二苄酯被用作亲电试剂，用于通过脯氨酸催化的C-糖基烷基醛的α-胺化反应，合成C-糖基α-氨基酸。它被用于光学活性吡唑烷衍生物的对映选择性合成。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Shengming Ma et al.
Organic letters, 6(13), 2193-2196 (2004-06-18)
[reaction: see text] Optically active pyrazolidine derivatives have been constructed by the Cu- and Pd-catalyzed asymmetric one-pot tandem addition-cyclization reaction of 2-(2',3'-dienyl)-beta-ketoesters, organic halides, and dibenzyl azodicarboxylate. The absolute configurations of the final products depend on the structure of the
[4+ 2] Cycloaddition reaction of dibenzyl azodicarboxylate and glycals.
Leblanc Y, et al.
Journal of the American Chemical Society, 111(8), 2995-3000 (1989)
Andrea Nuzzi et al.
Organic letters, 10(20), 4485-4488 (2008-09-16)
Non-natural axially and equatorially linked C-glycosyl alpha-amino acids (glycines, alanines, and CH2-serine isosteres) with either S or R alpha-configuration were prepared by D- and L-proline-catalyzed (de >95%) alpha-amination of C-glycosylalkyl aldehydes using dibenzyl azodicarboxylate as the electrophilic reagent.
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