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Merck

161241

Sigma-Aldrich

1-苯基-1-丙炔

99%

别名:

1-丙烯基苯, 1-炔丙基-1-苯, 1-甲基-2-苯乙炔, 3-苯基-2-丙炔, 甲基苯乙炔, 苯基甲基乙炔, (2-甲基乙炔基)苯

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$116.00
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About This Item

线性分子式:
C6H5C≡CCH3
CAS号:
分子量:
116.16
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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方案

99%

表单

liquid

折射率

n20/D 1.564 (lit.)

沸点

185 °C (lit.)

密度

0.928 g/mL at 25 °C (lit.)

官能团

phenyl

储存温度

2-8°C

SMILES字符串

CC#Cc1ccccc1

InChI

1S/C9H8/c1-2-6-9-7-4-3-5-8-9/h3-5,7-8H,1H3

InChI key

GHUURDQYRGVEHX-UHFFFAOYSA-N

一般描述

研究人员已经报道过环戊烯和1-苯基-1-丙炔的共催化反应。[1]研究人员采用程序升温脱附(temperature-programmed desorption)、X射线和双光子发射光谱研究了100K 下铜(111)上1-苯基-1-丙炔的成键性质。[2]1-苯基-1-丙炔是多巴胺-β羟化酶的抑制剂。[3]研究人员已经报道过通过TaCl5和 NbCl5进行1-苯基-1-丙炔的聚合。[4]

1-苯基-1-丙炔可作为各种化学反应的原料,如加成反应和聚合。[5]

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

143.6 °F - closed cup

闪点(°C)

62 °C - closed cup

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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G Colombo et al.
The Journal of biological chemistry, 259(24), 15017-15020 (1984-12-25)
The catalytic action of dopamine beta-hydroxylase on 1-phenyl-1-propyne results in concomitant loss of enzyme activity. At pH 5.5 and 25 degrees C, 1-phenyl-1-propyne inactivates dopamine beta-hydroxylase in a mechanism-based fashion. The inactivation rate is first-order, follows saturation kinetics, and is
(Arylimido)niobium(V)?Alkylidenes, Nb(CHSiMe3)(NAr)[OC(CF3)3](PMe3)2, That Enable to Proceed Living Metathesis Polymerization of Internal Alkynes
Izawa T and Nomura K
Macromolecules, 53(13), 5266-5279 (2020)
Youngku Sohn et al.
Langmuir : the ACS journal of surfaces and colloids, 23(24), 12185-12191 (2007-10-31)
The bonding properties of 1-phenyl-1-propyne (PP, C6H5CCCH3) on Cu(111) at 100 K have been studied using temperature-programmed desorption (TPD), and X-ray, ultraviolet, and two-photon photoemission spectroscopies (XPS, UPS, and 2PPE). In TPD, there is no evidence for dissociation. Multilayer desorption
Shuhuai Xiang et al.
Journal of the American Chemical Society, 136(16), 5832-5835 (2014-04-12)
Here we report a general method for the measurement of (13)C kinetic isotope effects at natural abundance for reactions that yield two or more products concurrently. We use, as an example, a recently reported Co-catalyzed reaction between cyclopentene and 1-phenyl-1-propyne.
Effect of organometallic cocatalysts on the polymerization of 1-phenyl-1-propyne by tantalum pentachloride (TaCl5) and niobium pentachloride (NbCl5).
Masuda T, et al.
Macromolecules, 18(11), 2109-2113 (1985)

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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