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化驗
≥98.0% (AT)
形狀
solid
光學活性
[α]20/D −73±2°, c = 3% in ethanol
mp
~260 °C
SMILES 字串
Cl.C[C@H](N[C@@H](C)c1ccccc1)c2ccccc2
InChI
1S/C16H19N.ClH/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16;/h3-14,17H,1-2H3;1H/t13-,14-;/m0./s1
InChI 密鑰
ZBQCLJZOKDRAOW-IODNYQNNSA-N
應用
(−)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used:
- To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylphosphine.
- As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides.
- As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenediolato) phosphate(V) anion using 31P NMR.
其他說明
对应的手性氨基化锂可作为碱,用于酮的对映选择性脱质子化反应。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Supramolecular assembly of chiral polyoxometalate complexes for asymmetric catalytic oxidation of thioethers
Journal of Materials Chemistry, 22(18), 9181-9188 (2012)
(R)-2, 2′-Binaphthoyl-(S, S)-DI (1-phenylethyl) aminophosphine. Scalable protocols for the syntheses of phosphoramidite (feringa) ligands
Organic Syntheses, 85, 238-238 (2008)
Large-scale synthesis and resolution of trisphat [tris (tetrachlorobenzenediolato) phosphate (v)] anion
The Journal of Organic Chemistry, 69(24), 8521-8524 (2004)
Tetrahedron Asymmetry, 2, 1-1 (1991)
The Journal of Organic Chemistry, 57, 3599-3599 (1992)
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