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Merck

143677

Sigma-Aldrich

2-(溴甲基)萘

96%

别名:

β-(溴甲基)萘, β-萘基甲基溴, (萘-2-基)甲基溴, 2-(溴甲基)萘, 2-萘基甲基溴, 2-萘甲基溴

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5 G
$102.00
25 G
$248.00
100 G
$846.00

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5 G
$102.00
25 G
$248.00
100 G
$846.00

About This Item

线性分子式:
C10H7CH2Br
CAS号:
分子量:
221.09
Beilstein:
636546
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

$102.00


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质量水平

方案

96%

沸点

213 °C/100 mmHg (lit.)

mp

51-54 °C (lit.)

官能团

bromo

储存温度

2-8°C

SMILES字符串

BrCc1ccc2ccccc2c1

InChI

1S/C11H9Br/c12-8-9-5-6-10-3-1-2-4-11(10)7-9/h1-7H,8H2

InChI key

RUHJZSZTSCSTCC-UHFFFAOYSA-N

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应用

2-溴甲基萘(2-BMN)可用作起始材料,用于合成2-(氟甲基)萘[1]、2-萘甲基叠氮[2]、2-萘甲醛[3]、二硒化物、双(2-萘甲基)[4]、1H-1,2,3-三唑、4,4′-(1,4-亚苯基)双[1-(2-萘甲基)。[5]

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B - Skin Sens. 1

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

230.0 °F - closed cup

闪点(°C)

110 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A novel and efficient method for the synthesis of dibenzyl diselenides
Tian F and Lu S
J. Chem. Res. (M), 2004(9), 632-633 (2004)
Probing the reactivity of o-phthalaldehydic acid/methyl ester: synthesis of N-isoindolinones and 3-arylaminophthalides
Mamidyala SK and Cooper MA
Chemical Communications (Cambridge, England), 49(75), 8407-8409 (2013)
Dimeric and trimeric triazole based molecules as a new class of Hsp90 molecular chaperone inhibitors
Terracciano S, et al.
European Journal of Medicinal Chemistry, 65(9), 464-476 (2013)
Silica-based magnetic manganese nanocatalyst-applications in the oxidation of organic halides and alcohols
Sharma RK, et al.
ACS sustainable chemistry & engineering, 4(3), 1123-1130 (2016)
Kuppuswamy Arumugam et al.
Inorganic chemistry, 46(8), 3283-3288 (2007-03-16)
The reaction of P4S10 with acyloins, RC(O)CH(OH)R, in refluxing dioxane, followed by the addition of alkylating agents, forms dithiolene thiophosphoryl thiolate compounds, (R2C2S2)P(S)(SR'), which are readily isolated and purified. The compounds that have been prepared and identified spectroscopically are those

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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