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Merck
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文件

113379

Sigma-Aldrich

氯(二甲基)苯基硅烷

98%

别名:

DMPSCl, 二甲基苯基氯硅烷, 二甲基苯基硅基氯, 苯基二甲基氯硅烷

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About This Item

线性分子式:
C6H5Si(CH3)2Cl
CAS号:
768-33-2
分子量:
170.71
Beilstein:
606292
EC號碼:
212-193-0
MDL號碼:
MFCD00000499
分類程式碼代碼:
12352002
PubChem物質ID:
24846878
NACRES:
NA.22

品質等級

100

化驗

98%

折射率

n20/D 1.509 (lit.)

密度

1.017 g/mL at 25 °C (lit.)

SMILES 字串

C[Si](C)(Cl)c1ccccc1

InChI

1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI 密鑰

KWYZNESIGBQHJK-UHFFFAOYSA-N

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相关类别

應用

用于手性硅基炔丙醇合成对映体富集联烯基硅烷的原酸酯克莱森重排反应。

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 1

閃點（°F）

143.6 °F - closed cup

閃點（°C）

62 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Carlton P Folster et al.
Dalton transactions (Cambridge, England : 2003), 49(45), 16125-16132 (2020-01-30)
The synthesis of a chloro-functionalized six-membered cyclosilazane (Si5N) is reported. Subsequent reductive polymerizations yielded low molecular weight polysilazanes. 1H and 29Si NMR characterization suggest the identity of the reducing metal influences the polysilazane structure. Optical characterization is consistent with extended
Ryan A Brawn et al.
Organic letters, 9(14), 2689-2692 (2007-06-15)
A convenient procedure for the synthesis of highly enantioenriched allenylsilanes by Johnson orthoester Claisen rearrangement of 1-silyl propargylic alcohols is described. Allenylsilanes are then used as carbon nucleophiles in three-component, Lewis acid mediated additions to in situ generated oxonium ions
Yixuan Han et al.
The Journal of chemical physics, 153(4), 044902-044902 (2020-08-06)
Density changes in thin polymer films have long been considered as a possible explanation for shifts in the thickness-dependent glass transition temperature Tg(h) in such nanoconfined systems, given that the glass transition is fundamentally associated with packing frustration during material
M Okamoto
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 112(6), 409-413 (1992-06-01)
The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosilane in xylene, were studied by high-performance liquid chromatography using carbamazepine and diphenylhydantoin as model compounds. From the elemental

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