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637106

Sigma-Aldrich

Iron(II,III) oxide

nanopowder, 50-100 nm particle size (SEM), 97% trace metals basis

Synonym(s):

Ferrosoferric oxide, Iron oxide black, Magnetite

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About This Item

Empirical Formula (Hill Notation):
Fe3O4
CAS Number:
Molecular Weight:
231.53
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

97% trace metals basis

form

nanopowder
spherical

surface area

6-8 m2/g , estimated

particle size

50-100 nm (SEM)

mp

1538 °C (lit.)

density

4.8-5.1 g/mL at 25 °C (lit.)

bulk density

0.84 g/mL

application(s)

battery manufacturing

SMILES string

O=[Fe].O=[Fe]O[Fe]=O

InChI

1S/3Fe.4O

InChI key

SZVJSHCCFOBDDC-UHFFFAOYSA-N

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General description

Iron(II,III) oxide nanopowder is a fine powder composed of iron oxide particles with a size ranging from 50-100 nm. It is also known as ferrous ferric oxide or ferrosoferric oxide. Iron(II,III) oxide is a reddish-brown, magnetic material that is stable and chemically inert. It is commonly used as a pigment in paints, coatings, and ceramics, and it is also used as a catalyst in many chemical reactions. As a nanopowder form, this iron(II,III) oxide has a large surface area, which makes it more effective as a catalyst.

Application

Iron(II,III) oxide (Fe3O4) can be used as a heterogeneous catalyst for the Fenton type oxidation of rhodamine B. It can be used as an anode material for the fabrication of lithium-ion batteries. Fe3O4 can also be utilized in the catalysis of the oxygen reduction reaction (ORR) in the anion exchange membrane fuel cell.

Analysis Note

XRD image is representative only; it is not lot specific

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Fenton-like oxidation of Rhodamine B in the presence of two types of iron (II, III) oxide
Xue X, et al.
Journal of Hazardous Materials, 166(1), 407-414 (2009)
Longitudinal 3He and proton imaging of magnetite biodistribution in a rat model of instilled nanoparticles.
Al Faraj A, et al.
Magnetic Resonance in Chemistry, 59(6), 1298-1303 (2008)
Cobalt-iron (II, III) oxide hybrid catalysis with enhanced catalytic activities for oxygen reduction in anion exchange membrane fuel cell
Wang C, et al.
Journal of Power Sources, 277(1), 147-154 (2015)
Enhanced electrochemical performance of template-free carbon-coated iron (II, III) oxide hollow nanofibers as anode material for lithium-ion batteries
Im ME, et al.
Journal of Power Sources, 284(1), 392-399 (2015)
A conceptually new type of bio-hybrid scaffold for bone regeneration.
Tampieri A, et al.
Nanotechnology, 22(1) (2011)

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