L6883
Lithium acetate dihydrate
reagent grade
Synonym(s):
Acetic acid lithium salt
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About This Item
Linear Formula:
CH3COOLi · 2H2O
CAS Number:
Molecular Weight:
102.02
Beilstein/REAXYS Number:
3564320
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.55
Recommended Products
grade
reagent grade
form
solid
composition
Lithium acetate, ≥63%
pH
≤9.5 (5% in solution)
mp
53-56 °C (lit.)
anion traces
chloride (Cl-): ≤0.003%
sulfate (SO42-): ≤100 ppm
cation traces
Fe: ≤20 ppm
Na: ≤50 ppm
SMILES string
[Li+].[H]O[H].[H]O[H].CC([O-])=O
InChI
1S/C2H4O2.Li.2H2O/c1-2(3)4;;;/h1H3,(H,3,4);;2*1H2/q;+1;;/p-1
InChI key
IAQLJCYTGRMXMA-UHFFFAOYSA-M
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General description
Lithium acetate dihydrate is one of the commercially available forms of lithium acetate. It is used as a precursor material for the synthesis of various lithium-based compounds. It is also used as a catalyst in several chemical reactions.
Application
Lithium acetate dihydrate (LiOAc.2H2O) can be used as a precursor material to synthesize:
It can also be used as a catalyst in the enantioselective synthesis of functionalized 1,3-thiazin-4-ones via N-heterocyclic carbene (NHC)-catalyzed [3 + 3] annulation of thioamides.
- Carbon-modified nanocrystalline LiFePO4 (LiFePO4/C) via sol-gel method using ferrous sulfate, phosphoric acid, citric acid, and polyethylene glycol.
- Lithium-graphite nanotubes (LGN) by chemical vapor deposition (CVD) method in the presence of copper with methane as the carbon source.
- Conductive polycrystalline solid-state electrolyte (Li4B7O12Cl) by reacting with boric acid and copper(II) chloride dihydrate in trihexyltetradecylphosphonium chloride via an ionothermal method.
It can also be used as a catalyst in the enantioselective synthesis of functionalized 1,3-thiazin-4-ones via N-heterocyclic carbene (NHC)-catalyzed [3 + 3] annulation of thioamides.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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