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Sigma-Aldrich

Ni(COD)(TSO-Ph)

≥95%

Synonym(s):

(1,5-Cyclooctadiene)(2,3,4,5-tetraphenylthiophene 1-oxide)nickel(0)

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About This Item

Empirical Formula (Hill Notation):
C36H32NiOS
Molecular Weight:
571.40
UNSPSC Code:
12352103
NACRES:
NA.21

Quality Level

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Application

Ni(COD)(TSO-Ph) is a bench-stable 18-electron nickel–olefin complex that can be used for a variety of reactions.


Reference

Structurally Diverse Bench-Stable Nickel(0) Pre-Catalysts: APractical Toolkit for In Situ Ligation Protocols

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Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The Engle lab strives to invent novel catalytic alkene and alkyne functionalization methods to expedite organic synthesis. These transformations offer a powerful platform for conversion of simple, abundant, and planar starting materials into densely functionalized, stereochemically complex products in a single step. To this end, the Engle lab has developed various substrate directivity strategies in which native functional groups can be temporarily masked with auxiliaries that are capable of reversibly binding the metal catalyst, thereby enhancing kinetic reactivity, suppressing unwanted side reactions, and facilitating high selectivity. The Engle lab works with us to make synthetically enabling directing groups, catalysts, and ligands readily available to the synthetic community for reaction discovery and small-molecule synthesis.

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