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903655

Sigma-Aldrich

1-Cyclohexyl-2-norbornene

Synonym(s):

1-Cyclohexylbicyclo[2.2.1]hept-2-ene

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About This Item

Empirical Formula (Hill Notation):
C13H20
CAS Number:
2237928-13-9
Molecular Weight:
176.30
UNSPSC Code:
12352200

form

liquid

reaction suitability

reaction type: C-H Activation
reagent type: catalyst

Application

1-Cyclohexyl-2-norbornene is a norbornene ligand developed in the lab of Guanbing Dong for us in norbornene/palladium catalysis. The catalytic system of 1-Cyclohexyl-2-norbornene, [PdCl(allyl)]2 (683396), and RuPhos (663131) can be used for the site-selective ortho functionalization of aryl iodides.1

Other Notes

Complementary site-selectivity in arene functionalization enabled by overcoming the ortho constraint in palladium/norbornene catalysis

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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