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Sigma-Aldrich

1-Methylimidazolium chloride

95%

Synonym(s):

1-Methylimidazole hydrochloride

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About This Item

Empirical Formula (Hill Notation):
C4H6N2 · HCl
CAS Number:
35487-17-3
Molecular Weight:
118.56
MDL number:
MFCD06798176
UNSPSC Code:
12352100
PubChem Substance ID:
57649996
NACRES:
NA.22

assay

≥94.5% (HPLC)
95%

impurities

≤1% water

SMILES string

Cl[H].Cn1ccnc1

InChI

1S/C4H6N2.ClH/c1-6-3-2-5-4-6;/h2-4H,1H3;1H

InChI key

STCBHSHARMAIOM-UHFFFAOYSA-N

Application

1-Methylimidazolium chloride behaves as a solvent and catalyst during the formation of 5-hydroxymethylfurfural from fructose and sucrose via acid-catalyzed dehydration.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Zhuang Wang et al.
Chemosphere, 185, 681-689 (2017-07-21)
Graphene and ionic liquids (ILs) released into the environment will interact with each other. So far however, the risks associated with the concurrent exposure of biota to graphene and ILs in the environment have received little attention. The research reported
Dehydration of fructose and sucrose into 5-hydroxymethylfurfural in the presence of 1-H-3-methyl imidazolium chloride acting both as solvent and catalyst.
Moreau C, et al.
J. Mol. Catal. A: Chem., 253(1), 165-169 (2006)
Ariyanti Sarwono et al.
Ultrasonics sonochemistry, 37, 310-319 (2017-04-22)
5-Hydroxymethylfurfural (HMF) has been identified as a promising biomass-derived platform chemical. In this study, one pot production of HMF was studied in ionic liquid (IL) under probe sonication technique. Compared with the conventional heating technique, the use of probe ultrasonic
Pankaj Attri et al.
PloS one, 8(7), e68970-e68970 (2013-07-23)
In this paper, we have examined the conductivity and interaction studies of ammonium and imidazolium based ionic liquids (ILs) with the newly synthesised low bandgap polymer (Poly(2-heptadecyl-4-vinylthieno[3,4-d]thiazole) (PHVTT)). Use of low bandgap polymers is the most suitable way to harvest
Najeh Maaloul et al.
Environmental science and pollution research international, 27(19), 23447-23463 (2019-01-04)
In this study, novel cellulose-bead-based biosorbents (CBBAS) were successfully synthesized from almond shell using a simple three-step process: (i) dissolution of bleached almond shell in ionic liquid (1-butyl-3-methylimidazolium chloride), (ii) coagulation of cellulose-ionic liquid solution in water and (iii) freeze-drying.
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