Skip to Content
MilliporeSigma
All Photos(1)

Documents

145262

Sigma-Aldrich

(Ethoxycarbonylmethyl)dimethylsulfonium bromide

97%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
C2H5O2CCH2S(CH3)2Br
CAS Number:
5187-82-6
Molecular Weight:
231.15
EC Number:
225-968-3
MDL number:
MFCD00830557
UNSPSC Code:
12352100
PubChem Substance ID:
24848710
NACRES:
NA.22

assay

97%

form

solid

mp

90-94 °C (lit.)

SMILES string

Br.CCOC(=O)C[S](C)C

InChI

1S/C6H13O2S.BrH/c1-4-8-6(7)5-9(2)3;/h4-5H2,1-3H3;1H/q+1;/p-1

InChI key

JXFPTJYKYKVENJ-UHFFFAOYSA-M

Related Categories

Application

(Ethoxycarbonylmethyl)dimethylsulfonium bromide was used in synthesis of α-sulfanyl-β-amino acid derivatives by using nanocrystalline magnesium oxide. It was used during cyclopropanation of (-)-(S)-2-(p-tolylsulfinyl)cyclopent-2-enone.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Constrained cycloalkyl analogues of glutamic acid: stereocontrolled synthesis of (+)-2-aminobicyclo [3.1. 0] hexane-2, 6-dicarboxylic acid (LY354740) and its 6-phosphonic acid analogue
Krysiak J, et al.
Tetrahedron Asymmetry, 21(11), 1486-1493 (2010)
Synthesis of a-sulfanyl-?-amino acid derivatives by using nanocrystalline magnesium oxide.
Kantam ML, et al.
Tetrahedron, 66(27), 5042-5052 (2010)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service