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83750

Rhodium(III) nitrate hydrate

~36% rhodium (Rh) basis

Synonim(y):

Rhodium trinitrate

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Rozmiar/SKUDostępnośćCena netto
250 mg
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956,00 zł
1 g
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2690,00 zł
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9820,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
N3O9Rh · xH2O
Numer CAS:
Masa cząsteczkowa:
288.92 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Form:
powder

956,00 zł


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Quality Segment

form

powder

reaction suitability

core: rhodium

concentration

~36% Rh

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

SMILES string

O.[Rh+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.H2O.Rh/c3*2-1(3)4;;/h;;;1H2;/q3*-1;;+3

InChI key

QKLCKVVKVHCMIC-UHFFFAOYSA-N

General description

Rhodium(III) nitrate hydrate is a crystallinecompound widely used in the field of catalysis, electro-plating, and glassindustry

Application

Rhodium(III) nitrate hydrate can be used as a precursor:
  • To synthesize Rh-doped catalysts for various chemical transformations.
  • With iron(III) nitrate nonahydrate to synthesis Fe–Rh/TiO2 catalysts for hydrogenation reaction.
  • For Ethene Hydroformylation, a bimetallic Rh/Co catalyst is synthesized by combining Rhodium(III) nitrate hydrate with Co(NO3)2 .6H2O.
  • For the simultaneous electrodeposition of Cu and Rh from an aqueous nitrate solution.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.
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Ta pozycja
309206325902237957
description

~36% rhodium (Rh) basis

description

~10 % (w/w) (Rh in >5 wt. % HNO3)

description

99.9% trace metals basis

description

99.8% trace metals basis

form

powder

form

liquid

form

powder and chunks

form

crystals and lumps

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

concentration

~36% Rh

concentration

~10 % (w/w) (Rh in >5 wt. % HNO3), ≥5.0% (NaOH basis (wt% HNO3, titration))

concentration

-

concentration

-

reaction suitability

core: rhodium

reaction suitability

core: rhodium

reaction suitability

core: scandium

reaction suitability

core: yttrium

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

application(s)

-

application(s)

-


Słowo ostrzegawcze

Danger

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

PPE (środki ochrony indywidualnej)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Muta. 2 - Ox. Sol. 1 - Skin Corr. 1B - Skin Sens. 1A

Klasa składowania

5.1A - Strongly oxidizing hazardous materials



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Certyfikaty analizy (CoA)

Lot/Batch Number

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Questions

1–4 of 4 Questions  
  1. What is the purity of Rhodium(III) nitrate hydrate?

    1 answer
    1. The purity of this material is not determined. However, the Rhodium content is reported on a lot to lot basis and may range from 35.0 - 37.5% by ICP. This information is reported in the Certificate of Analysis. Please see the link below to review a sample or lot specific Certificate:
      https://www.sigmaaldrich.com/product/aldrich/83750#product-documentation

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  4. Is this compound packaged under inert atmosphere?

    1 answer
    1. Yes, this product is hygroscopic and packaged under an argon.

      Helpful?

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