791016

RockPhos

97%, solid

• Synonim(y): 2-Di(tert-butyl)phosphino-2′,4′,6′-triisopropyl-3-methoxy-6-methylbiphenyl, Di-tert-butyl(2′,4′,6′-triisopropyl-3-methoxy-6-methyl-[1,1′-biphenyl]-2-yl)phosphine
• Wzór empiryczny (zapis Hilla): C₃₁H₄₉OP
• Numer CAS: 1262046-34-3
• Masa cząsteczkowa: 468.69
• UNSPSC Code: 12352112
• PubChem Substance ID: 329768254
• NACRES: NA.22
• MDL number: MFCD20922895

Właściwości

• Nazwa produktu: RockPhos, 97%
• Quality Segment: 100
• product line: Buchwald Ligand
• assay: 97%
• form: solid
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand; reaction type: Cross Couplings
• mp: 121-131 °C
• functional group: phosphine
• storage temp.: 15-25°C
• SMILES string: CC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C(C)(C)C)C(C)(C)C)=C(OC)C=C1
• InChI: 1S/C31H49OP/c1-19(2)23-17-24(20(3)4)28(25(18-23)21(5)6)27-22(7)15-16-26(32-14)29(27)33(30(8,9)10)31(11,12)13/h15-21H,1-14H3
• InChI key: CVLLAKCGAFNZHJ-UHFFFAOYSA-N

Opis

Application

RockPhos is a biphenyl-based phosphine ligand used with Pd(0) catalyst for carbon-carbon and carbon-heteroatom bond formation reactions.
It can also be employed in the:

• 2-fluroethoxylation of bromo-chalcones in the presence of palladium catalyst.
• Conversion of aryl chlorides into aryl methoxides using RockPhos Pd G3 as a catalyst.

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable