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XantPhos Pd G3

95%, solid

Synonim(y):

[(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate

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Rozmiar/SKUDostępnośćCena netto
250 mg
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255,00 zł
191,25 zł
1 g
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759,00 zł
5 g
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3140,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
C52H45NO4P2PdS
Numer CAS:
Masa cząsteczkowa:
948.35
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

191,25 zł

Cena katalogowa255,00 złZaoszczędź 25%

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Nazwa produktu

XantPhos Pd G3, 95%

Quality Segment

product line

Buchwald precatalyst Generation 3

assay

95%

form

solid

feature

generation 3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium, reagent type: catalyst
reaction type: Cross Couplings

mp

164-167 °C (decomposition)

functional group

phosphine

SMILES string

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC3(C)c4cccc(P(c5ccccc5)c6ccccc6)c4Oc7c(cccc37)P(c8ccccc8)c9ccccc9

InChI

1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

AJVXPGQYAKUTGX-UHFFFAOYSA-M

General description

XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Application

XantPhos Pd G3 may be used in the following processes:
  • Negishi cross-coupling reaction during the synthesis of palmerolides.
  • Aminocarbonylation of heteroaryl bromides with carbon monoxide (CO) in the presence of triethylamine.
  • Coupling between polyglycosyl thiols and aglycon halides by C-S bond formation.
For small scale and high throughput uses, product is also available as ChemBeads (932213)
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900329794228763047
description

95%

description

-

description

95%

description

-

reaction suitability

reaction type: Negishi Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reagent type: catalyst
core: palladium, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling

reaction suitability

reaction type: Sonogashira Coupling, reaction type: Negishi Coupling, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Heck Reaction

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reaction type: Suzuki-Miyaura Coupling

assay

95%

assay

-

assay

95%

assay

-

form

solid

form

powder

form

solid

form

solid

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

164-167 °C (decomposition)

mp

-

mp

-

mp

188-196 (decomposition)


Klasa składowania

11 - Combustible Solids

Co się dzieje?

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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