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453048
Dichlorobis(tri-o-tolylphosphine)palladium(II)
97%, solid
Synonim(y):
PdCl2[P(o-Tol)3]2
Wybierz wielkość
| Do Państwa/SKU | Dostępność | Cena netto |
|---|---|---|
1 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 296,00 zł |
5 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 816,00 zł |
Informacje o tej pozycji
296,00 zł
Nazwa produktu
Dichlorobis(tri-o-tolylphosphine)palladium(II), 97%
Quality Segment
assay
97%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
core: palladium
mp
280 °C (dec.) (lit.)
SMILES string
Cl[Pd]Cl.Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C
InChI
1S/2C21H21P.2ClH.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;;/h2*4-15H,1-3H3;2*1H;/q;;;;+2/p-2
InChI key
OTYPIDNRISCWQY-UHFFFAOYSA-L
General description
Application
Catalyst for C-C and C-N coupling reaction.
- Reaction of tributyltin enolates, prepared in situ from tributyltin methoxide and enol acetates, with aryl bromides.
- Coupling reaction of aryl bromides with vinylic acetates.
- Negishi-Reformatsky coupling reaction of aryl bromides with ethyl 2-(tributylstannyl)acetates.
- Synthesis of (E)-methyl 3-(7-indolyl)-2-methacrylate, via Heck reaction.
- Synthesis of imidazopyrimidine derivatives.[1]
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Ta pozycja | |||
|---|---|---|---|
| assay 97% | assay 95% | assay 97% | assay - |
| reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst |
| form solid | form solid | form solid | form solid |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 280 °C (dec.) (lit.) | mp 270 °C (dec.) (lit.) | mp 230-300 °C (decomposition) | mp - |
![Dichloro[2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) 97%](/deepweb/assets/sigmaaldrich/product/structures/351/904/a38f7a0d-b8a0-448f-b949-4b983e7f1eb3/640/a38f7a0d-b8a0-448f-b949-4b983e7f1eb3.png)
Klasa składowania
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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