444561

Tris-(8-hydroxyquinoline)aluminum

99.995% trace metals basis

• Synonim(y): 8-Hydroxyquinoline aluminum salt, Alq₃, Aluminum 8-hydroxyquinolinate, Aluminum oxinate, Tris-(8-hydroxyquinolinato)aluminum
• Wzór empiryczny (zapis Hilla): C₂₇H₁₈AlN₃O₃
• Numer CAS: 2085-33-8
• Masa cząsteczkowa: 459.43
• NACRES: NA.23
• PubChem Substance ID: 24868131
• UNSPSC Code: 12352103
• EC Number: 218-227-0
• MDL number: MFCD00191693

Właściwości

• description: Emissive Layer
• Quality Segment: 100
• assay: 99.995% trace metals basis
• form: powder
• mp: >300 °C (lit.)
• orbital energy: LUMO -3.3 eV , LUMO 3.3 eV
• OLED device performance: ITO/MoO₃/NPD/Alq₃/BPhen/LiF/Al;
  • Color: green
  • Max. Luminance: 20000 Cd/m²
  • Max. EQE: 1.2 %
  • Turn-On Voltage: 2.8 V
  , ITO/NPD/CBP:Ir(ppy)₃/BCP/Alq₃/Mg:Al;
  • Color: green
  • Max. Luminance: 100000 Cd/m²
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V
  , ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: red
  • Max. Luminance: 24529 Cd/m²
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V
  , ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: green
  • Max. Luminance: 207839 Cd/m²
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
  , ITO/m-MTDATA/NPD/TTPhPhB/Alq₃/LiF/Al;
  • Color: blue
  • Max. Luminance: 9100 Cd/m²
  • Max. EQE: 2.5 %
  • Turn-On Voltage: 3.2 V
• SMILES string: O([Al](Oc1cccc2cccnc12)Oc3cccc4cccnc34)c5cccc6cccnc56
• InChI: 1S/3C9H7NO.Al/c3*11-8-5-1-3-7-4-2-6-10-9(7)8;/h3*1-6,11H;/q;;;+3/p-3
• InChI key: TVIVIEFSHFOWTE-UHFFFAOYSA-K

Opis

General description

Alq₃ crystals exist in two isomeric states, meridional and facial isomers. A third isomeric state ( γ) was studied by X-ray diffraction, the δ-Alq3 transforms into γ-form at ~180°C. Mechanism of the Alq₃ phosphorescence has been studied.

Application

Key green-light emitting and electron transport material for OLEDs.

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Informacja o środkach bezpieczeństwa

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Klasa składowania: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves