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40727

1,3-Dimethyl-2-imidazolidinone

≥99.0% (GC), for headspace GC analysis

Synonim(y):

N,N′-Dimethylethyleneurea, DMEU, DMI

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Rozmiar/SKUDostępnośćCena netto
100 mL
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377,00 zł
1 L
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2640,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
C5H10N2O
Numer CAS:
Masa cząsteczkowa:
114.15
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-304-8
Beilstein/REAXYS Number:
108808
MDL number:
Assay:
≥99.0% (GC)
Form:
liquid

377,00 zł


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Quality Segment

assay

≥99.0% (GC)

form

liquid

refractive index

n20/D 1.472 (lit.)

bp

224-226 °C (lit.)

solubility

toluene: soluble(lit.), water: miscible

density

1.056 g/mL at 25 °C (lit.)

SMILES string

CN1CCN(C)C1=O

InChI

1S/C5H10N2O/c1-6-3-4-7(2)5(6)8/h3-4H2,1-2H3

InChI key

CYSGHNMQYZDMIA-UHFFFAOYSA-N

General description

1,3-Dimethyl-2-imidazolidinone (DMI) is an imidazolidine derivative. It is reported to act as a promoter by minimizing the formation of dialkylation byproducts and accelerating the rate of monoalkylation of γ-butyrolactone. Conversion of CO2 to form lower alcohols by homogeneous catalytic hydrogenation using DMI as solvent has been investigated.

Application

1,3-Dimethyl-2-imidazolidinone may be used:
  • As substitute solvent for hexamethylphosphoric triamide (HMPA) in the synthesis of 1,2-bis(trimethylsilyl)benzene.
  • As solvent during the α-regioselective prenylation of imine.
  • As component of mobile phase for the size-exclusion chromatographic analysis of cellulose.

Other Notes

Solvent used in various synthetic organic transformations. Studied in the formation of functionally stabilized hydrosilanediyl-transition metal complexes produced photochemically from arylsilanes.
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Ta pozycja
19345340725I601
description

≥99.0% (GC), for headspace GC analysis

description

reagent grade

description

absolute, over molecular sieve (H2O ≤0.04%), ≥99.5% (GC)

description

96%

assay

≥99.0% (GC)

assay

97.5 % (GC)

assay

≥99.5% (GC)

assay

96%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

solubility

water: miscible, toluene: soluble(lit.)

solubility

toluene: soluble(lit.), water: miscible

solubility

water: miscible, toluene: soluble(lit.)

solubility

-

bp

224-226 °C (lit.)

bp

224-226  °C, 224-226 °C (lit.)

bp

224-226 °C (lit.)

bp

-

density

1.056 g/mL at 25 °C (lit.)

density

1.056 g/mL at 25 °C (lit.), 1.056  g/mL at 25 °C

density

1.056 g/mL at 25 °C (lit.)

density

-

refractive index

n20/D 1.472 (lit.)

refractive index

n20/D 1.472 (lit.)

refractive index

-

refractive index

-


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signalword

Danger

flash_point_f

219.2 °F - closed cup

flash_point_c

104 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B

Klasa składowania

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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