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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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347116
Samarium(II) iodide solution
0.1 M in THF, contains samarium chips as stabilizer
Synonim(y):
Samarium diiodide
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
25 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 351,00 zł |
100 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 361,00 zł |
4 x 25 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 849,00 zł |
1 L | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 2380,00 zł |
Informacje o tej pozycji
351,00 zł
form
liquid
Quality Segment
contains
samarium chips as stabilizer
reaction suitability
core: samarium, reagent type: catalyst
reaction type: Reductions, reagent type: reductant
concentration
0.1 M in THF
density
0.922 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
I[Sm]I
InChI
1S/2HI.Sm/h2*1H;/q;;+2/p-2
InChI key
UAWABSHMGXMCRK-UHFFFAOYSA-L
Application
- Benzannulated pyrrolizidines and indolizidines by SmI2-induced cyclizations of indole derivatives.
- Chiral 4-substituted 2-oxazolidinones and 5,5-disubstituted oxazolidinones through asymmetric Reformatsky type reaction.
- γ-Aminoalkyl substituted γ-butyrolactones via ketyl-alkene coupling reaction.
It can also be used in:
- Reduction of conjugated double and triple bonds into alkenes using SmI2/H2O/amine mixtures.
- Conversion of β-hydroxyketones into 1,3-diols by SmI2/H2O/Et3N.
- Selective reduction of 6-membered lactones to the corresponding diols/triols using SmI2-H2O reagent system.
SmI2 is an effective single-electron reducing agent for the promotion of ketone-olefin, ketyl aryl cyclizations, and pinacol coupling reactions under mild conditions. Often both intramolecular and intermolecular couplings proceed in a highly stereoselective fashion. It is also used in the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.
Packaging
Legal Information
1 of 1
Ta pozycja | ||
|---|---|---|
| description 0.1 M in THF, contains samarium chips as stabilizer | description anhydrous, powder, ≥99.9% trace metals basis | description 99.9% trace metals basis |
| reaction suitability core: samarium, reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability core: samarium, reagent type: catalyst |
| form liquid | form powder | form powder |
| Quality Level 200 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. - | storage temp. - |
| density 0.922 g/mL at 25 °C | density - | density - |
| contains samarium chips as stabilizer | contains - | contains - |
Słowo ostrzegawcze
Danger
Kody zagrożeń
Narządy docelowe
Central nervous system, Respiratory system
supp_hazards
Klasa składowania
4.3 - Hazardous materials which set free flammable gases upon contact with water
Temperatura zapłonu (°F)
-2.2 °F - closed cup - Solvent
Temperatura zapłonu (°C)
-19 °C - closed cup - Solvent
PPE (środki ochrony indywidualnej)
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - STOT SE 3 - Water-react. 3
Wykazy regulacyjne
Wykazy regulacyjne dotyczą głównie produktów chemicznych. Można w nich podawać ograniczoną liczbę informacji na temat produktów niechemicznych. Brak wpisu oznacza, że żaden ze składników nie znajduje się w wykazie. Użytkownik odpowiada za zagwarantowanie bezpiecznego i zgodnego z prawem stosowania produktu.
109-99-9 + 7440-19-9
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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