If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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337773
Chlorodiisopropylphosphine
Bardziej ekologiczna alternatywa
96%, liquid
Synonim(y):
Diisopropylphosphine chloride
Wybierz wielkość
| Do Państwa/SKU | Dostępność | Cena netto |
|---|---|---|
5 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 367,00 zł |
25 g | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 1060,00 zł |
Informacje o tej pozycji
367,00 zł
Nazwa produktu
Chlorodiisopropylphosphine, 96%
Quality Segment
assay
96%
form
liquid
reaction suitability
reagent type: ligand
reaction type: Arylations
greener alternative product characteristics
Catalysis
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sustainability
Greener Alternative Product
refractive index
n20/D 1.475 (lit.)
bp
69 °C/33 mmHg (lit.)
density
0.959 g/mL at 25 °C (lit.)
functional group
phosphine
greener alternative category
SMILES string
CC(C)P(Cl)C(C)C
InChI
1S/C6H14ClP/c1-5(2)8(7)6(3)4/h5-6H,1-4H3
InChI key
JZPDBTOWHLZQFC-UHFFFAOYSA-N
General description
Application
- To synthesize p-styryldiisopropylphosphine by reacting with 4-chlorostyrene via Grignard reaction.
- As a phosphination reagent in combination with [Cp2Zr(1-butene)(DMAP)] (Cp=cyclopentadienyl; DMAP= 4-(dimethylamino)pyridine)) for the zirconophosphination of alkynes to form zirconoalkenylphosphines.
- A luminescent mixed-donor platinum POCN pincer complex via cyclometalation process.
1 of 1
Ta pozycja | |||
|---|---|---|---|
| description 96% | description 96% | description 1.0 M in THF | description 1.0 M in 2-methyltetrahydrofuran |
| reaction suitability reagent type: ligand | reaction suitability reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings | reaction suitability reagent type: ligand | reaction suitability reagent type: ligand |
| assay 96% | assay 96% | assay - | assay - |
| form liquid | form liquid | form liquid | form liquid |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| bp 69 °C/33 mmHg (lit.) | bp 320 °C (lit.) | bp - | bp - |
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Corr. 1B
Klasa składowania
3 - Flammable liquids
wgk
WGK 3
flash_point_f
39.2 °F - closed cup
flash_point_c
4 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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