303232

3-Nitro-2-pyridinesulfenyl chloride

95%

• Synonim(y): (3-Nitro-2-pyridyl)sulfenyl chloride, 2-(Chlorosulfanyl)-3-nitropyridine, 3-Nitropyridinyl-2-sulfenyl chloride, [(3-Nitropyridin-2-yl)sulfanyl]chlorane
• Wzór empiryczny (zapis Hilla): C₅H₃ClN₂O₂S
• Numer CAS: 68206-45-1
• Masa cząsteczkowa: 190.61
• NACRES: NA.22
• PubChem Substance ID: 24858307
• UNSPSC Code: 12352100
• MDL number: MFCD00274609
• Assay: 95%

Właściwości

• Quality Segment: 100
• assay: 95%
• reaction suitability: reagent type: protection reagent; reactivity: thiol reactive
• mp: 205 °C (dec.) (lit.)
• solubility: dichloromethane: soluble(lit.)
• functional group: nitro
• storage temp.: 2-8°C
• SMILES string: [O-][N+](=O)c1cccnc1SCl
• InChI: 1S/C5H3ClN2O2S/c6-11-5-4(8(9)10)2-1-3-7-5/h1-3H
• InChI key: WTKQMHWYSBWUBE-UHFFFAOYSA-N

Opis

General description

The 3-nitro-2-pyridinesulphenyl (Npys) moiety is useful as a protecting-activating group for cysteine, particularly in the synthesis of cyclic and unsymmetrical disulfides. The stability of NpysCl was studied in various solvents.

Application

3-Nitro-2-pyridinesulfenyl chloride (NpysCl) was employed as the starting material for the synthesis of N-, O- and S-Npys-protected amino acid.

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Informacja o środkach bezpieczeństwa

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Eye Dam. 1 - Skin Corr. 1B
• Klasa składowania: 8A - Combustible corrosive hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges