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Diphenylphosphine

98%, liquid

Cechy związane ze zrównoważonym rozwojem

Synonim(y):

HPPh2, Ph2PH

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Rozmiar/SKUDostępnośćCena netto
10 g
Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności
751,00 zł
50 g
Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności
1460,00 zł

Informacje o tej pozycji

Wzór liniowy:
(C6H5)2PH
Numer CAS:
Masa cząsteczkowa:
186.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
EC Number:
212-591-4
MDL number:
Beilstein/REAXYS Number:
742504

751,00 zł


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Nazwa produktu

Diphenylphosphine, 98%

vapor pressure

2 mmHg ( 110 °C)

Quality Segment

assay

98%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

sustainability

Sustainability features

refractive index

n20/D 1.625 (lit.)

bp

280 °C (lit.)

density

1.07 g/mL at 25 °C (lit.)

functional group

phosphine

greener alternative category

SMILES string

C1(PC2=CC=CC=C2)=CC=CC=C1

InChI

1S/C12H11P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

InChI key

GPAYUJZHTULNBE-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. Click here for more information.

Application

Deprotonation of Ph2PH gives diphenylphosphide, used for synthesis of novel phosphine ligands, Wittig-Horner reagents, and phosphonium salts; source of phosphorus-centered radicals.
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Ta pozycja
380768567728464872
description

98%

description

0.5 M in THF

description

98%

description

0.5 M in THF

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reagent type: ligand, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Negishi Coupling

reaction suitability

reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reagent type: ligand, reaction type: Stille Coupling, reaction type: Negishi Coupling

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Hiyama Coupling

reaction suitability

reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reagent type: ligand, reaction type: Hiyama Coupling, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling

assay

98%

assay

-

assay

98%

assay

-

form

liquid

form

liquid

form

-

form

-

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

-

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

density

1.07 g/mL at 25 °C (lit.)

density

0.929 g/mL at 25 °C

density

-

density

0.925 g/mL at 25 °C


Piktogramy

FlameExclamation mark

Słowo ostrzegawcze

Danger

Kody zagrożeń

Hazard Classifications

Eye Irrit. 2 - Pyr. Liq. 1 - Skin Irrit. 2 - STOT SE 3

Narządy docelowe

Respiratory system

Klasa składowania

4.2 - Pyrophoric and self-heating hazardous materials

Co się dzieje?

WGK 3

Temperatura zapłonu (°F)

230.0 °F - closed cup

Temperatura zapłonu (°C)

110 °C - closed cup

PPE (środki ochrony indywidualnej)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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