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225754

Allylmagnesium bromide solution

1.0 M in diethyl ether

Synonim(y):

(Prop-2-en-1-yl)magnesium bromide, 2-Propenylmagnesium bromide, Allyl magnesium bromide, Allylbromomagnesium, Allylmagnesiumbromide, Bromo-2-propenylmagnesium

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Rozmiar/SKUDostępnośćCena netto
100 mL
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619,00 zł
800 mL
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1360,00 zł

Informacje o tej pozycji

Wzór liniowy:
CH2=CHCH2MgBr
Numer CAS:
Masa cząsteczkowa:
145.28
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
969335

619,00 zł


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Quality Segment

reaction suitability

reaction type: Grignard Reaction

packaging

Kilo-Lab™ of , Sure/Seal™ of

concentration

1.0 M in diethyl ether

density

0.851 g/mL at 25 °C

SMILES string

Br[Mg]CC=C

InChI

1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1

InChI key

FEMBXICCJNZMMC-UHFFFAOYSA-M

General description

Allylmagnesium bromide solution serves as a selective nucleophile toward aza-aromatic heterocycles.

Application

Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:
  • 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine
  • tarchonanthuslactone
  • (+)-preussin
  • polyhydroxylated quinolizidine alkaloids

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Kilo-Lab is a trademark of Merck KGaA, Darmstadt, Germany
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256609302430245550
description

1.0 M in diethyl ether

description

1.0 M in diethyl ether

description

1.0 M in dibutyl ether

description

2.0 M in diethyl ether

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

reaction suitability

reaction type: Grignard Reaction

density

0.851 g/mL at 25 °C

density

0.851 g/mL at 25 °C

density

0.856 g/mL at 25 °C

density

1.043 g/mL at 25 °C

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

concentration

1.0 M in diethyl ether

concentration

1.0 M in diethyl ether

concentration

1.0 M in dibutyl ether

concentration

2.0 M in diethyl ether

packaging

Sure/Seal™ of , Kilo-Lab™ of

packaging

Sure/Pac™ of

packaging

Sure/Seal™ of

packaging

Sure/Seal™ of


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Słowo ostrzegawcze

Danger

Narządy docelowe

Central nervous system

supp_hazards

Klasa składowania

4.3 - Hazardous materials which set free flammable gases upon contact with water

Co się dzieje?

WGK 1

Temperatura zapłonu (°F)

-40.0 °F - closed cup

Temperatura zapłonu (°C)

-40 °C - closed cup

PPE (środki ochrony indywidualnej)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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