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Bis(benzonitrile)palladium(II) chloride

95%, powder

Cechy związane ze zrównoważonym rozwojem

Synonim(y):

Benzonitrile, palladium complex, Bis(benzonitrile)dichloropalladium(II), Bis(benzonitrile)palladium(II) chloride, Bis(phenylnitrile)dichloropalladium, Dibenzonitrilepalladium dichloride, Dichlorobis(benzonitrile)palladium, Dichlorobis(benzonitrile)palladium(II), Dichlorobis(phenyl cyanide)palladium, Palladium dichloride bis(benzonitrile), Palladium(II) chloride bis(benzonitrile) complex

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Rozmiar/SKUDostępnośćCena netto
1 g
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390,00 zł
10 g
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3070,00 zł
2302,50 zł

Informacje o tej pozycji

Wzór liniowy:
(C6H5CN)2PdCl2
Numer CAS:
Masa cząsteczkowa:
383.57
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
238-085-3
MDL number:
Beilstein/REAXYS Number:
3981730

390,00 zł


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Nazwa produktu

Bis(benzonitrile)palladium(II) chloride, 95%

Quality Segment

assay

95%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Sustainability features

mp

131 °C (lit.)

greener alternative category

SMILES string

Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2

InChI

1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

WXNOJTUTEXAZLD-UHFFFAOYSA-L

General description

Bis(benzonitrile)palladium(II) chloride is a coordination compound used as a catalyst in the Suzuki Cross-Coupling reaction.


We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:
  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins
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741248323373205885
description

95%

description

-

description

99.995%

description

ReagentPlus®, 99%

assay

95%

assay

-

assay

99.995%

assay

99%

reaction suitability

reaction type: Heck Reaction, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Sonogashira Coupling, core: palladium, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

reaction type: Heck Reaction, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Cross Couplings, reaction type: Negishi Coupling, reagent type: ligand, reaction type: Stille Coupling, reagent type: catalyst
core: palladium, reaction type: Hiyama Coupling

reaction suitability

reaction type: Heck Reaction, reagent type: catalyst, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, core: palladium, reaction type: Negishi Coupling, reaction type: Hiyama Coupling

reaction suitability

reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, core: palladium, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reaction type: Hiyama Coupling, reaction type: Heck Reaction

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

mp

131 °C (lit.)

mp

-

mp

678-680 °C (lit.)

mp

678-680 °C (lit.)

greener alternative category

Aligned,

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-

greener alternative category

-

greener alternative category

-

sustainability

Greener Alternative Product

sustainability

-

sustainability

-

sustainability

-


Klasa składowania

11 - Combustible Solids

Co się dzieje?

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

PPE (środki ochrony indywidualnej)

Eyeshields, Gloves, type N95 (US)



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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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