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215554

Copper(I) iodide

99.999% trace metals basis

Synonim(y):

Cuprous iodide

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Do Państwa/SKUDostępnośćCena netto
5 g
Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności
489,00 zł
25 g
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821,00 zł
100 g
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2110,00 zł
1 kg
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24 210,00 zł

Informacje o tej pozycji

Wzór liniowy:
CuI
Numer CAS:
Masa cząsteczkowa:
190.45
PubChem Substance ID:
eCl@ss:
38150105
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
231-674-6
MDL number:
Assay:
99.999% trace metals basis
Form:
powder and chunks
Solubility:
dilute aqueous acid: insoluble(lit.)

489,00 zł


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vapor pressure

10 mmHg ( 656 °C)

Quality Segment

assay

99.999% trace metals basis

form

powder and chunks

reaction suitability

core: copper

impurities

≤15.0 ppm Trace Metal Analysis

bp

1290 °C/1 atm (decomp)(lit.)

mp

605 °C (lit.)

solubility

dilute aqueous acid: insoluble(lit.)

density

5.62 g/mL at 25 °C (lit.)

SMILES string

[Cu+].[I-]

InChI

1S/Cu.HI/h;1H/q+1;/p-1

InChI key

LSXDOTMGLUJQCM-UHFFFAOYSA-M

Application

Copper(I) iodide can be used as a catalyst for:
  • For arylation of pyrazole and derivatives by coupling arenediazonium species under mild and ligand-free conditions.
  • Selective cross-coupling of dibromo alkenes and heteronucleophiles which leads to numerous building blocks such as 1-bromoenamides, ynamides, ketene N, N-acetals, 1-bromoenol ethers, ynol ethers, ketene O, O-acetals, and vinyl phosphonates.
  • Stereospecific and the regioselective reaction of silacyclopropanes with carbonyl compounds.
It can also be used as a starting material in the preparation of diphenylphosphinepyridine-derivatives (PyrPHOS)-copper iodide complexes which are suitable for use in OLEDs.

Features and Benefits

  • Low toxicity
  • Mild reaction condition
  • High purity ensures reproducibility and avoids cocatalysis by contaminants.
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Ta pozycja
7920632055408.18311
description

99.999% trace metals basis

description

99.995% trace metals basis

description

98%

description

for synthesis

form

powder and chunks

form

powder

form

powder

form

solid

solubility

dilute aqueous acid: insoluble(lit.)

solubility

-

solubility

-

solubility

0.08 g/L

assay

99.999% trace metals basis

assay

99.995% trace metals basis

assay

98%

assay

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

mp

605 °C (lit.)

mp

605 °C (lit.)

mp

605 °C (lit.)

mp

588 °C

vapor pressure

10 mmHg ( 656 °C)

vapor pressure

10 mmHg ( 656 °C)

vapor pressure

10 mmHg ( 656 °C)

vapor pressure

-


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1A - STOT RE 1 Oral

target_organs

Thyroid

Klasa składowania

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Certyfikaty analizy (CoA)

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Questions

1–6 of 6 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. If the purity of 99.999% for Product 215554, Copper (I) Iodide is based solely on trace metal content, then what is the chemical purity of this product?

    1 answer
    1. We do not report a chemical purity for this product, however, an approximation of the purity can be determined by taking the value for the Copper content reported on the Certificate of Analysis and dividing it by the theoretical content of 33.4%.  (It is a an approximation because there could be other Copper containing impurities present that may contribute to the value).

      Helpful?

  4. What is Product 215554, Copper (I) Iodide soluble in?

    1 answer
    1. According to the 13th edition of the chemicals encyclopedia published by the Royal Society of Chemistry, it is decomposed by concentrated Sulfuric Acid and Nitric Acid, insoluble in water, practically insoluble in ethanol and dilute acids, soluble in aqueous solutions of ammonia, alkali cyanides, thiosulfates, and iodides.

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  5. Product 215554, Copper (I) Iodide has turned grayish in color.  Is it still good?

    1 answer
    1. This compound is light sensitive.  It is cream colored when first it is first produced, then slowly turns grayish in color because of its photosensitivity.  Chemical purity is not significantly compromised by modest homogeneous appearance changes.

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  6. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

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