The polystyrene microparticles offered for sale are not sterile.
Although autoclaving is a common method of sterilization, polystyrene microparticles are not autoclavable. Filter sterilization is also not a practical method. There are no protocols available for sterilizing polystyrene microparticles. From the remaining methods for sterilization, it should be possible to either sterilize in 70% ethanol for 30 minutes and then rinse away the ethanol with sterile water. For small batches, UV radiation would be another option.