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210013

Sigma-Aldrich

Hydriodic acid

contains no stabilizer, distilled, 57 wt. % in H2O, 99.99% trace metals basis

Synonym(s):

Hydriotic acid

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About This Item

Empirical Formula (Hill Notation):
HI
CAS Number:
10034-85-2
Molecular Weight:
127.91
MDL number:
MFCD00011347
UNSPSC Code:
12352106
PubChem Substance ID:
329752069
NACRES:
NA.21

Assay

99.99% trace metals basis

form

liquid

does not contain

stabilizer

concentration

57 wt. % in H2O

bp

127 °C (lit.)

mp

-50 °C

density

1.701 g/mL at 25 °C

storage temp.

room temp

SMILES string

I

InChI

1S/HI/h1H

InChI key

XMBWDFGMSWQBCA-UHFFFAOYSA-N

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General description

Hydriodic acid (HI) along with red phosphorus (HI/red P) plays the role of a reducing agent for the preparation of methamphetamine. HI/Phosphorous causes the reduction of various polycyclic quinones. HI also participates as a reducing agent for the conversion of various polyarene quinones, hydroquinones and phenols to the corresponding aromatic hydrocarbons.
Hydriodic acid is hydrogen iodide gas dissolved in water. It is a strong acid generally used as a reducing agent.

Application

Hydriodic acid may be used in the synthesis of trideuterio-[13C]-methyl iodide and [13C]-methyl iodide.

Pictograms

CorrosionEnvironment
GHS05,GHS09

Signal Word

Danger

Hazard Statements

H290,H314,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A practical laboratory route to the synthesis of trideuteriomethyl-[13C] iodide.
Coumbarides GS, et al.
Journal of Labelled Compounds & Radiopharmaceuticals, 46(4), 291-296 (2003)
Patnaik P.
A Comprehensive Guide to the Hazardous Properties of Chemical Substances, 123 (2007)
Efficient reduction of polycyclic quinones, hydroquinones, and phenols with hydriodic acid.
Konieczny M and Harvey RG.
The Journal of Organic Chemistry, 44(26), 4813-4816 (1979)
Methamphetamine synthesis via hydriodic acid/red phosphorus reduction of ephedrine.
Skinner HF.
Forensic Science International, 48(2), 123-134 (1990)
Kazumasa Wakamatsu et al.
Pigment cell & melanoma research, 22(4), 474-486 (2009-06-06)
Pheomelanogenesis is a complex pathway that starts with the oxidation of tyrosine (or DOPA, 3,4-dihydroxyphenylalanine) by tyrosinase in the presence of cysteine, which results in the production of 5-S-cysteinyldopa and its isomers. Beyond that step, relatively little has been clarified
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